Abstract
Polyvinyl guanidineacetic (PVG) was synthesized by the chemical grafting using poly (vinyl alcohol) (PVA) and guanidineacetic acid. The fourier transform infrared (FTIR), thermogravimetry (TG) and 1H nuclear magnetic resonance (1H NMR) results showed that the guanidineacetic groups were successfully introduced into the PVA. The effects of the amount of catalyst and reaction time on the PVG grafting rate were investigated. The PVG/non-woven fabrics (NWF) composite membrane as a heterogeneous catalyst for biodiesel production was successfully prepared by the solvent phase inversion. The effects of mass ratio of methanol/soybean oil, the IEC values of the composite membranes and reaction temperature on the transesterification conversions using the composite membrane for biodiesel were studied. The soybean oil conversion of 98.2% was obtained by the composite membranes under the optimum reaction conditions of reaction temperature of 338 K, methanol/oil mass ratio of 3:1, reaction time of 120 min and the alkali amount of catalytic membrane 18.0 mmol. After five runs, the conversion declined only 2.1%. And the kinetics of the reaction catalyzed by the composite membrane was performed as a first order reaction with an activation energy of 40.614 kJ/mol and pre-exponential factor of 7.60 × 104. The conversions obtained from the model are in good agreement with the experimental data. The quality of the biodiesel met the biodiesel requirements of Chinese Standard (GB/T 20828) and European Standard (EN 14214).
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References
Reyero I, Moral A, Bimbela F et al (2016) Fuel 182:668–676
Navajas A (2018) Fuel 211:173–181
Dang TH, Chen BH, Lee DJ (2013) Bioresour Technol 145:175–181
Farobie O, Yukihiko M (2015) Bioresour Technol 191:306–311
Gurunathan B, Ravi A (2015) Bioresour Technol 188:124–127
Bateni H, Saraeian A, Able C et al (2018) Biofuel Biorefin Technol 8:57–100
Bateni H, Saraeian A, Able C (2017) Biofuel Res J 4:668–690
Zeng QH, Liu QL, Broadwell I et al (2010) J Membr Sci 349:237–243
Radivojevic D, Avramescu M, Seshan K et al (2008) Appl Catal A 351:159–165
He BQ, Shao YX, Liang MZ et al (2015) Fuel 159:33–39
Zhang WD, Qing WH, Chen N et al (2014) J Membr Sci 451:285–292
Zazil CG, Maria Isabel LB, Emmanuel HN et al (2017) Polym Bull 74:2741–2754
Zhu ML, He B, Shi WY et al (2010) Fuel 89:2299–2304
Tantirungrotechai J, Thepwatee S, Yoosuk B (2013) Fuel 106:279–284
Shi WY, Li HB, Zhou R et al (2016) Bioresour Technol 201:43–48
Knothe G (2000) J Am Oil Chem Soc 77:489–493
Birla A, Singh B, Upadhyay SN et al (2012) Bioresour Technol 106:95–100
Gao LJ, Xu W, Xiao GM (2017) Chem Eng Process 122:122–127
Shi WY, He BQ, Li JX et al (2011) Bioresour Technol 102:5389–5393
Mariana SAS, Deborath MR, Tonetto GM (2018) Energy 164:264–274
Shi WY, He BQ, Ding JC et al (2010) Bioresour Technol 101:1501–1505
Shi WY, He BQ, Li JX et al (2013) Bioresour Technol 129:100–107
Phan AN, Phan TM (2008) Fuel 87:3490–3496
Bateni H, Karimi K (2016) RSC Adv 6:34492–34500
Naveenkumar R, Baskar G (2019) Bioresour Technol 280:493–496
Xu W, Gao LJ, Xiao GM (2015) Fuel 159:484–490
Monika H, Claudia N, Sonia A et al (2019) Fuel Process Technol 185:1–7
Singh AK, Fernando SD (2007) Chem Eng Technol 30:1716–1720
Acknowledgements
The authors gratefully acknowledge the financial support by National Natural Science Foundation of China (Grant Nos. 51403052), the Central Plains Thousand People Program-Top Young Talents in Central Plains (No, ZYQR201810135), the Program for Henan Science and Technology Development (No. 192102210038) and the funding for the Project supported by the Training plan for Young Scholar in Colleges and Universities in Henan Province (No.2017GGJS151).
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Shi, W., Li, H., Yu, B. et al. Biodiesel Production Catalyzed by Polyvinyl Guanidineacetic Membrane. Catal Lett 151, 153–163 (2021). https://doi.org/10.1007/s10562-020-03279-9
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DOI: https://doi.org/10.1007/s10562-020-03279-9