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Thermoregulated Phase-Transfer Pd Nanocatalyst for Selective Hydrogenation of 1,5-Cyclooctadiene at Atmospheric Hydrogen Pressure

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Abstract

Thermoregulated phase-transfer Pd nanocatalyst was firstly employed in the selective hydrogenation of 1,5-cyclooctadiene (1,5-COD) at atmospheric hydrogen pressure. Under the optimal conditions, > 99% conversion and 95% selectivity to cyclooctene (COE) were obtained. The Pd nanocatalyst can be easily separated from products and directly reused. The turnover frequency (TOF) of 1411 h−1 is the highest value ever reported among Pd nanocatalysts at atmospheric hydrogen pressure.

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Data Availability

The data generated and analyzed during the current study are available from the corresponding author on reasonable request.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (21173031).

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Authors and Affiliations

  1. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, People’s Republic of China

    Zhaohui Zhao & Yanhua Wang

Authors
  1. Zhaohui Zhao
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  2. Yanhua Wang
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Contributions

The study conception and design were conducted by Yanhua Wang. Material preparation, data collection and analysis were performed by Zhaohui Zhao. The first draft of the manuscript was written by Zhaohui Zhao and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to Yanhua Wang.

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Zhao, Z., Wang, Y. Thermoregulated Phase-Transfer Pd Nanocatalyst for Selective Hydrogenation of 1,5-Cyclooctadiene at Atmospheric Hydrogen Pressure. Catal Lett 150, 2703–2708 (2020). https://doi.org/10.1007/s10562-020-03174-3

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  • DOI: https://doi.org/10.1007/s10562-020-03174-3

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