Abstract
A simple, efficient and environmentally benign method has been discussed for the synthesis of aldehydes and ketones by the oxidative decarboxylation of phenylacetic acid under ligand free condition using simple, efficient, preparatively easy, magnetically recoverable and low cost spinel CuFe2O4 nanoparticles. The catalyst was characterised using powder-XRD, FTIR, FE-SEM, EDX, VSM and HRTEM. The recyclability was examined and the results showed that the catalyst remained almost equally active up to five consecutive cycles.
Graphic Abstract
Spinel Structured Copper Ferrite is a very efficient nano catalyst for Oxidative decarboxylation of Phenyl acetic acids and can be reused up to five cycles without significant loss in catalytic activity.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Feng Q, Song Q (2014) J Org Chem 79:1867
Jun CH (2004) Chem Soc Rev 33:610
Dzik WI, Lange PP, Goossen L (2012) J Chem Sci 3:2671
Rodriguez N, Goossen L (2011) J. Chem. Soc. Rev. 40:5030
Mete TB, Khopade TM, Bhat RG (2017) Tetrahedron Lett 58:2822
Shang R, Yang ZW, Wang Y, Zhang SL, Liu L (2010) J Am Chem Soc 132:14391
Shang R, Huang Z, Chu L, Fu Y, Liu L (2011) Org Lett 13:4240
Shang R, Ji DS, Chu L, Fu Y, Liu L (2011) Angew Chem Int Ed 50:4470
Song Q, Feng Q, Zhou M (2013) Org Lett 15:5990
Feng Q, Song Q (2014) Adv Synth Catal 356:1697
Song Q, Feng Q, Yang K (2014) Org Lett 16:624
Hussain FL, Suri M, Namdeo A, Borah G, Dutta D, Goswami T, Pahari P (2019) Catal Commun 124:76
Kumar V, Mariappan CR, Azmi R, Moock D, Indris S, Bruns M, Ehrenberg H, Prakash GV (2017) ACS Omega 2:6003
Pendashteh A, Rahmanifar MS, Kaner RB, Mousavi MF (2014) Chem Commun 50:1972
Wu H, Lou Z, Yang H, Shen G (2015) Nanoscale 7:1921
Goyal A, Bansal S, Kumar V, Singh J, Singhal S (2015) Appl Surf Sci 324:877
Nassar MY, Khatab M (2016) RSC Adv. 6:79688
Ghose J, Murthy KSRC (1996) J Catal 162:359
Salker AV, Gurav SM (2000) J Mater Sci 35:4713
Hosseini SA, Niaei A, Salari D, Nabavi SR (2012) Ceram Int 38:1655
Zhai X, Yang W, Li M, Lv G, Liu J, Zhang X (2013) Carbon 65:277
Bazgir A, Hosseini G, Ghahremanzadeh R (2013) ACS Comb. Sci. 15:530
Zhang R, Miao C, Shen Z, Wang S, Xia C, Sun W (2012) ChemCatChem 4:824
Huynh MM, Do DP, Tran TN, Nguyen HKH, Tran HQ, Luu TX (2018) Catal Lett 148:924
Rahman T, Borah G, Gogoi PK (2019) J Chem Sci 131:4.
Rahman T, Borah G, Gogoi PK (2018) J Indian Chem Soc 95:795
Chavan P, Naik LR (2018) Sens. Actuators 272:28
Vergis BR, Krishna RH, Kottam N, Nagabhushana BM, Sharath R, Darukaprasad B (2018) J. Nanostruct. Chem. 8:1
Baruah D, Konwar D (2015) Catal Commun 69:68
Acknowledgements
The authors acknowledge the analytical services provided by STIC Kochi, SAIF NEHU Shillong, CIF IIT Guwahati, CSIC Dibrugarh University. The authors are also grateful to UGC, New Delhi, India for the financial support under the scheme SAP-DRS-I (2016-2021) and the Department of Science and Technology for financial assistance under the DST-FIST program.
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Rahman, T., Borah, G. & Gogoi, P.K. Spinel Structured Copper Ferrite Nano Catalyst with Magnetic Recyclability for Oxidative Decarboxylation of Phenyl Acetic Acids. Catal Lett 150, 2267–2272 (2020). https://doi.org/10.1007/s10562-020-03131-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-020-03131-0