Abstract
Boron-rich alloy boron suboxide (B6O) as a novel metal-free photocatalyst was recently explored for photocatalytic CO2 reduction and water splitting. However, to broaden the potential applications of B6O in the field, further improving its activity and understanding its fundamental chemical properties are essential. Herein, transition metal doping (Cr or Co) is designed to engineer the band structure of B6O via a solid state reaction. The valence band edge of Cr or Co doped B6O is proposed to be more positive than that of pristine B6O while the original conduction band of B6O is not much influenced by doping, contributing to the better light harvesting ability and lower charge recombination rate of doped B6O. The photocatalytic and photoelectrochemical (PEC) performances of doped B6O were therefore remarkably enhanced. The apparent quantum yields (AQY) of 20 wt% Cr or Co doped B6O are much higher than that of pristine B6O. In addition, the 20 wt% Cr doped B6O exhibits the best electrical conductivity and photocatalytic performance compared with the Co doped B6O and pristine B6O. The present work demonstrates a facile and effective strategy to engineer the band structure and reduce the charge migration resistance of B6O.
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Walter MG, Warren EL, McKone JR, Boettcher SW, Mi QX, Santori EA, Lewis NS (2010) Chem Rev 110:6446–6473
Panwar NL, Kaushik SC, Kothari S (2011) Renew Sustain Energy Rev 15:1513–1524
Kudo A, Miseki Y (2009) Chem Soc Rev 38:253–278
Lewis NS, Nocera DG (2006) Proc Natl Acad Sci USA 103:15729–15735
Luo ZB, Wang T, Zhang JJ, Li CC, Li HM, Gong JL (2017) Angew Chem Int Ed 56:12878–12882
Li JP, Ren DJ, Wu ZX, Xu J, Bao YJ, He S, Chen Y (2018) J Colloid Interface Sci 530:78–87
Pei L, Lv BH, Wang SB, Yu ZT, Yan SC, Abe R, Zou ZG (2018) ACS Appl Energy Mater 1:4150–4157
Nie N, Zhang LY, Fu JW, Cheng B, Yu JG (2018) Appl Surf Sci 441:12–22
Cen YL, Shi JJ, Zhang M, Wu M, Du J, Guo WH, Zhu YH (2019) J Colloid Interface Sci 546:20–31
Park J, Kim S, Sim Y, Yoon OJ, Han MS, Yang HS, Kim YY, Jhon YM, Kim J, Seong MJ (2016) J Alloys Compd 659:38–43
Hou YD, Zhu YS, Xu Y, Wang XC (2014) Appl Catal B 156–157:122–127
Guan ZJ, Luo WJ, Xu Y, Tao QC, Wen X, Zou ZG (2016) ACS Appl Mater Interfaces 8:5432–5438
Wang XC, Maeda K, Thomas A, Takanabe K (2009) X G, Carlsson JM, Domen K, Antonietti M. Nat Mater 8:76–80
Wang F, Ng WKH, Yu JC, Zhu HJ, Li CH, Zhang L, Liu ZF, Li Q (2012) Appl Catal B 111–112:409–414
Zhu XJ, Zhang TM, Sun ZJ, Chen HL, Guan J, Chen X, Ji HX, Du PW, Yang SF (2017) Adv Mater 29:1605776
Liu G, Niu P, Yin LC, Cheng HM (2012) J Am Chem Soc 134:9070–9073
Fang YX, Wang XC (2017) Angew Chem Int Ed 56:15506–15518
Liu JK, Wen SH, Hou Y, Zuo F, Beran GJ, Feng PY (2013) Angew Chem Int Ed 52:3241–3245
Shi L, Li P, Zhou W, Wang T, Chang K, Zhang HB (2016) Kako k, Liu GG, Ye JH. Nano Energy 28:158–163
Liu GG, Meng XG, Zhang HB, Zhao GX, Pang H, Wang T, Li P, Kako T, Ye JH (2017) Angew Chem Int Ed 56:5570–5574
Wang SJ, Swingle SF, Ye H, Fan FR, Cowley AH, Bard AJ (2012) J Am Chem Soc 134:11056–11059
Yan DJ, Liu PL, Tao Q, Zhu PW, Liu JK, Luo HA (2019) Sol RRL 3:1900014
Olofsson M, Lundstrom T (1997) J Alloys Compd 25:91–95
Ektarawong A, Simak SI, Hultman L, Birch J, Tasnádi F, Wang F, Alling B (2016) J Chem Phys 144:134503
Su FZ, Mathew SC, Lipner G, Fu XZ, Antonietti M, Blechert S, Wang XC (2010) J Am Chem Soc 132:16299–16301
Chang C, Fu Y, Hu M, Wang CY, Shan GQ, Zhu LY (2013) Appl Catal B 142–143:553–560
Yu Y, Zeng JF, Chen CJ, Xie Z, Guo RS, Liu ZL, Zhou XC, Yong Y, Zheng ZJ (2014) Adv Mater 26:810–815
Xie M, Tang JC, Kong LS, Lu WH, Natarajan V, Zhu F, Zhan JH (2019) Chem Eng J 360:1213–1222
Han Q, Hu CG, Zhao F, Zhang ZP, Chen N, Qu LT (2015) J Mater Chem A 3:4612–4619
Sun ZC, Yu ZQ, Liu YY, Shi C, Zhu MS, Wang AJ (2019) J Colloid Interface Sci 533:251–258
Shi HF, Chen GQ, Zhang CL, Zou ZG (2014) ACS Catal 4:3637–3643
Wang FZ, Li WJ, Gu SN, Li HD, Ren CJ, Liu XT (2018) Eur J Inorg Chem 2018:2564–2573
Fu JW, Xu QL, Low JX, Jiang CJ, Yu JG (2019) Appl Catal B 243:556–565
Song YH, Gu JM, Xia KX, Yi JJ, Chen HX, She XJ, Chen ZG, Ding C, Li HM, Xu H (2019) Appl Surf Sci 467–468:56–64
Zhang YK, Jin ZL (2019) Catal Lett 149:34–48
Chen XF, Zhang JS, Fu XZ, Antonietti M, Wang XC (2009) J Am Chem Soc 131:11658–11659
Wang XC, Chen XF, Thomas A, Fu XZ, Antonietti M (2009) Adv Mater 21:1609–1612
Yue B, Li QY, Iwai H, Kako T, Ye JH (2011) Sci Technol Adv Mater 12:034401
Wang YG, Wang YZ, Chen YT, Yin CC, Zuo YH, Cui LF (2015) Mater Lett 139:70–72
Xie SM, Chen H, Solodkyi I, Vasylkiv O, Tok AIY (2015) Scr Mater 99:69–72
Pelaez M, Nolan NT, Pillai SC, Seery MK, Falaras P, Kontos AG, Dunlop PSM, Hamilton JWJ, Byrne JA, Shea KO, Entezari MH, Dionysiou DD (2012) Appl Catal B 125:331–349
Zhang YH, Gong MD, Liu X, Ji LJ, Yang ZL, Zhu XS (2019) J Mater Sci 54:2975–2989
Baumann TF, Gash AE, Chinn SC, Sawvel AM, Maxwell RS, Satcher JH (2005) Chem Mater 17:395–401
Sreethawong T, Puangpetch T, Chavadej S, Yoshikawa S (2007) J Power Sources 165:861–869
Varley JB, Lordi V, Miglio A, Hautier G (2014) Phys Rev B 90:045205
Kalanur SS, Yoo IH, Eom K, Seo H (2018) J Catal 357:127–137
Ennaceur MM, Terreault B (2000) J Nucl Mater 280:33–38
Zhang KH, Bersch BM, Joshi J, Addou R, Cormier CR, Zhang CX, Xu K, Briggs NC, Wang K, Subramanian S, Cho K, Fullerton-Shirey S, Wallace RM, Vora PM, Robinson JA (2018) Adv Funct Mater 28:1706950
Reddy CV, Babu B, Shim J (2017) Mater Sci Eng B 223:131–142
Wang YP, Zhu T, Zhang YF, Kong XZ, Liang SQ, Cao GZ, Pan AQ (2017) J Mater Chem A 5:18448–18456
Cai PW, Huang JH, Chen JX, Wen ZH (2017) Angew Chem Int Ed 56:4858–4861
Yin B, Cao XX, Pan AQ, Luo ZG, Dinesh S, Lin JD, Tang Y, Liang SQ, Cao GZ (2018) Adv Sci 5:1800829
Zhang K, Zhang G, Qu JH, Liu HJ (2018) Small 14:1802760
Yan DJ, Liu JK, Fu XC, Liu PL, Luo HA (2019) J Mater Sci 54:6151–6163
Hirakawa T, Nosaka Y (2002) Langmuir 18:3247–3254
Liu CH, Wang F, Zhu SS, Xu Y, Liang Q, Chen ZD (2018) J Colloid Interface Sci 530:403–411
Liu HL, Lu ZH, Yue L, Liu J, Gan ZH, Shu C, Zhang T, Shi J, Xiong R (2011) Appl Surf Sci 257:9355–9361
Cao J, Yang ZH, Xiong WP, Zhou YY, Peng YR, Li X, Zhou CY, Xu R, Zhang YR (2018) Chem Eng J 353:126–137
Niu XY, Yan WJ, Zhao HL, Yang JK (2018) Appl Surf Sci 440:804–813
Yan DJ, Fu XC, Shang ZC, Liu JK, Luo HA (2019) Chem Eng J 361:853–861
Humam SB, Nguyen HH, Regmi C, Gyawali G, Joshi B, Lee SW (2019) Ceram Int 45:4230–4236
Yang H, Xu B, Yuan SS, Zhang QT, Zhang M, Ohnoc T (2019) Appl Catal B 243:513–521
Wang FX, Septina W, Chemseddine A, Adbi FF, Friedrich D, Bogdanoff P, Krol RVD, Tilley SD, Berglund SP (2017) J Am Chem Soc 139:15094–15103
Ahn HJ, Yoon KY, Kwak MJ, Park J, Jang JH (2018) ACS Catal 8:11932–11939
Chang H, Shang ZC, Kong QQ, Liu PL, Liu JK, Luo HA (2019) Chem Eng J 370:314–321
Jiao ZB, Zhang Y, Chen T, Dong QS, Lu GX, Bi YP (2014) Chem Eur J 20:2654–2662
Malengreaux CM, Pirard SL, Leonard G, Mahy JG, Herlitschke M, Klobes B, Hermann R, Heinrichs B, Bartlett JR (2017) J Alloys Compd 691:726–738
Zhao HY, Fan ZR, Fu QM, Wang H, Hu Z, Tao H, Zhong XD, Ma ZB, Jia TT (2018) J Mater Sci 53:15340–15347
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This work was financially supported by the Scientific Research Fund of Hunan Provincial Education Department (18B065) and the Natural Science Foundation of Hunan Province (2019JJ50595).
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Yang, Q., Liu, J., Yan, D. et al. Enhanced Photocatalytic CO2 Reduction and Water Splitting Over a Boron-Rich Alloy Boron Suboxide (B6O) via Cr or Co Doping. Catal Lett 150, 2497–2509 (2020). https://doi.org/10.1007/s10562-020-03111-4
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DOI: https://doi.org/10.1007/s10562-020-03111-4