Abstract
Sonolysis could be more practical for water treatment than traditional catalytic methods in some specific situations. However, the practical application is limited by the low degradation rate. In this work, the Cr doped SrTiO3 was prepared by hydrothermal method, and the Cr-doping results in the decreased crystal symmetry, which leads to the rough surface and a large number of pores of the sample. The appearance of a large number of holes increases the specific surface area and enhances the gas adsorption performance of the sample, which can promote the cavitation. The optimized Cr-doped SrTiO3 can degrade 95.4% rhodamine B (5 mg/L) in 10 min under ultrasound irradiation (53 kHz, 350 W). Furthermore, the improvement of sonolysis degradation with the Cr doped SrTiO3 is universal for dyes, such as methyl blue (MB), methyl orange (MO) and rhodamine B (RhB). The role of active species in ultrasonic catalysis and the synergistic mechanism of ultrasound and catalyst were systematically studied by adding sacrificial agents and changing the reaction atmosphere. This work indicates that the incorporation of finely modified inorganic particles is effective for efficient water treatment.
Graphic Abstract
Similar content being viewed by others
References
Wang Y, Cheng R, Wen Z, Zhao L (2012) Chem Eng J 203:277–284
Glaze WH, Kang JW, Chapin DH (1987) Ozone Sci Eng 9:335–352
O’Shea KE, Dionysiou DD (2012) J Phys Chem Lett 3:2112–2113
Gültekin I, Ince NH (2007) J Environ Manag 85:816–832
Suslick KS (1990) Science 247:1439–1445
Chen X, Dai J, Shi G, Li L, Wang G, Yang H (2016) Ultrason Sonochem 29:172–177
Lee G, Ibrahim S, Kittappa S, Park H, Park CM (2018) Ultrason Sonochem 44:64–72
Qiu P, Li W, Kang K, Park B, Luo W, Zhao D, Khim J (2014) J Mater Chem A 2:16452–16458
Suslick KS, Doktycz SJ, Flint EB (1990) Ultrasonics 28:280–290
Ashokkumar M, Grieser F (2005) J Am Chem Soc 127:5326–5327
Shchukin DG, Skorb E, Belova V, Möhwald H (2011) Adv Mater 23:1922–1934
Roldugin V, Tikhonov N (2002) Doklady Phys Chem 383:84–87
Hong K-S, Xu H, Konishi H, Li X (2010) J Phys Chem Lett 1:997–1002
Tu S, Huang H, Zhang T, Zhang Y (2017) Appl Catal B 219:550–562
Ouyang S, Tong H, Umezawa N, Cao J, Li P, Bi Y, Zhang Y, Ye J (2012) J Am Chem Soc 134:1974–1977
Hu Y, Tan OK, Pan JS, Yao X (2004) J Phys Chem B 108:11214–11218
Salvador P, Gutiérrez C (1984) J Electroanal Chem Interfacial Electrochem 160:117–130
Wang L, Zhou Y, Timoshenko J, Liu S, Qiao Q, Kisslinger K, Cuiffo M, Chuang Y-C, Zuo X, Xue Y, Guo Y, Pan C, Li H, Nam C-Y, Bliznakov S, Liu P, Frenkel AI, Zhu Y, Rafailovich MH (2019) ACS Catal 9:1446–1456
Shirai S, Sato S, Suzuki TM, Jinnouchi R, Ohba N, Asahi R, Morikawa T (2018) J Phys Chem C 122:1921–1929
Zhang H, Qiao J, Li G, Li S, Wang G, Wang J, Song Y (2018) Ultrason Sonochem 42:356–367
Zhou M, Yang H, Xian T, Li RS, Zhang HM, Wang XX (2015) J Hazard Mater 289:149–157
Zhu L, Ghosh T, Park C-Y, Meng Z-D, Oh W-C (2012) Chin J Catal 33:1276–1283
Wu Y, Song L, Zhang S, Wu X, Zhang S, Tian H, Ye J (2013) Catal Commun 37:14–18
Farhadi S, Siadatnasab F, Khataee A (2017) Ultrason Sonochem 37:298–309
Song L, Zhang S, Wu X, Wei Q (2012) Ultrason Sonochem 19:1169–1173
Lv M, Xie Y, Wang Y, Sun X, Wu F, Chen H, Wang S, Shen C, Chen Z, Ni S, Liu G, Xu X (2015) Phys Chem Chem Phys 17:26320–26329
Hui J, Zhang G, Ni C, Irvine JTS (2017) Chem Commun 53:10038–10041
Lan S, Feng J, Xiong Y, Tian S, Liu S, Kong L (2017) Environ Sci Technol 51:6560–6569
Wang Y, Chen L, Chen C, Xi J, Cao H, Duan X, Xie Y, Song W, Wang S (2019) Appl Catal B 254:283–291
Darvishi Cheshmeh Soltani R, Jorfi S, Ramezani H, Purfadakari S (2016) Ultrason Sonochem 28:69–78
Ghosh T, Ullah K, Nikam V, Park C-Y, Meng Z-D, Oh W-C (2013) Ultrason Sonochem 20:768–776
Acknowledgements
This work was supported by Anhui Provincial Natural Science Foundation (1908085ME119),the National Key Research and Development Program of China (2016YFA0401004, 2017YFA0402904), Anhui Initiative in Quantum Information Technologies (AHY100000), the National Natural Science Foundation of China (51627901) and the Open Programs for the Key Science & Technology Infrastructures of Chinese Academy of Sciences.
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Zhu, L., Gu, W., Zou, W. et al. Enhancing the Sonolysis Efficiency of SrTiO3 Particles with Cr-Doping. Catal Lett 150, 562–572 (2020). https://doi.org/10.1007/s10562-019-03008-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-019-03008-x