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Reaction Orders of the Hydrogenation of Nitrate and Nitrite in Water over a Nickel Catalyst

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Abstract

The hydrogenations of nitrate and nitrite in water were investigated using a Raney Ni catalyst and reduced Ni catalyst. For determination of the reaction orders, reduced Ni is more appropriate than Raney Ni due to the fact that Raney Ni has an intrinsic hydrogen on its surface and is more readily oxidized during the reaction. Based on the reaction orders of the reactants, it was revealed that the adsorption of hydrogen gas on the Ni surface was weaker than those of nitrate and nitrite.

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Acknowledgement

This work was partly supported by JSPS KAKENHI Grant Number JP19K05562.

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Authors and Affiliations

  1. Graduate School of Science and Engineering for Research, University of Toyama, Gofuku, Toyama, 930-8555, Japan

    Yukina Ogawa, Arata Sodeno, Miku Takatani & Tsutomu Osawa

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  1. Yukina Ogawa
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  2. Arata Sodeno
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  3. Miku Takatani
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  4. Tsutomu Osawa
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Correspondence to Tsutomu Osawa.

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Ogawa, Y., Sodeno, A., Takatani, M. et al. Reaction Orders of the Hydrogenation of Nitrate and Nitrite in Water over a Nickel Catalyst. Catal Lett 150, 291–300 (2020). https://doi.org/10.1007/s10562-019-02945-x

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