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β-CD-SO3H: Synthesis, Characterization and Its Application for the Synthesis of Benzylpyrazolyl Naphthoquinone and Pyrazolo Pyranopyrimidine Derivatives in Water

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Abstract

Green and economical method has been reported for the synthesis of benzylpyrazolyl naphthoquinone and pyrazolo pyranopyrimidines in water at room temperature by using β-CD-SO3H. β-Cyclodextrin supported sulfonic acid was prepared by simple one step procedure and characterized by FT-IR spectrum, 1H NMR, 13C NMR spectra, TGA, EDAX, XRD, BET surface area analysis and acid–base titration. The present protocol is environmental benign due to heterogeneous reusable catalyst and green reaction medium. This methodology provides excellent yield of the desired product with short reaction time at room temperature, easy workup procedure and no need of column chromatographic separation. Pyrazolyl derivatives are of much importance because this fragment is a key moiety in numerous biologically active compounds.

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Acknowledgements

The authors would like to thank Department of Chemistry, Shivaji University, Kolhapur for providing research facility.

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Authors and Affiliations

  1. Department of Chemistry, Shivaji University, Kolhapur, 416004, India

    Audumbar Patil, Shivanand Gajare, Gajanan Rashinkar & Rajashri Salunkhe

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  1. Audumbar Patil
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  2. Shivanand Gajare
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  3. Gajanan Rashinkar
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  4. Rajashri Salunkhe
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Correspondence to Rajashri Salunkhe.

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Patil, A., Gajare, S., Rashinkar, G. et al. β-CD-SO3H: Synthesis, Characterization and Its Application for the Synthesis of Benzylpyrazolyl Naphthoquinone and Pyrazolo Pyranopyrimidine Derivatives in Water. Catal Lett 150, 127–137 (2020). https://doi.org/10.1007/s10562-019-02928-y

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