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Highly Selective Hydrogenation of Furfural to Furan-2-ylmethanol over Zeolitic Imidazolate Frameworks-67-Templated Magnetic Cu–Co/C

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Abstract

Highly selective hydrogenation of furfural to furan-2-ylmethanol (FM) in isopropanol was achieved over a novel magnetic Cu–Co/C derived from zeolitic imidazolate frameworks prepared by galvanic replacement reaction. Furfural conversion and FM selectivity (FMS) are 100% and 97.2%, respectively, at 200 °C. FMS was held around 95% after 5-times recycle of the Cu–Co/C. In addition, cinnamaldehyde was completely converted with 96.8% of phenylpropanol selectivity over the Cu–Co/C at 150 °C.

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Acknowledgements

This work was supported by the Key Project of Joint Fund from the National Key Research and Development Program of China (Grant 2018YFB0604602) and a Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions.

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Authors and Affiliations

  1. Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining & Technology, Xuzhou, 221116, Jiangsu, China

    Zhi-Xin Li, Xian-Yong Wei, Zheng Yang, Min Zhang, Xing-Long Meng, Shuo Niu, Di Zhang & Zhi-Min Zong

  2. State Key Laboratory of High-Efficiency Coal Utilization and Green Chemical Engineering, Ningxia University, Yinchuan, 750021, Ningxia, China

    Xian-Yong Wei

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  1. Zhi-Xin Li
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Li, ZX., Wei, XY., Yang, Z. et al. Highly Selective Hydrogenation of Furfural to Furan-2-ylmethanol over Zeolitic Imidazolate Frameworks-67-Templated Magnetic Cu–Co/C. Catal Lett 150, 178–184 (2020). https://doi.org/10.1007/s10562-019-02925-1

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