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Magnetic Mesoporous Silica Nanocomposite Functionalized with Palladium Schiff Base Complex: Synthesis, Characterization, Catalytic Efficacy in the Suzuki–Miyaura Reaction and α-Amylase Immobilization

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Abstract

Magnetic mesoporous silica nanocomposite, Fe3O4-MCM-41, was functionalized with N-(2-aminoethyl)-3-aminopropyltrimethoxysilane (AEAPS) and then condensed with 5,5′-methylene bis(salicylaldehyde), followed by N(4)-phenylthiosemicarbazide to produce a ONS Schiff base grafted nanocomposite. Finally, by adding palladium(II) acetate, the palladium Schiff base complex was immobilized on magnetic nanocomposite. The characterization of new nanocomposites was carried out by means of several techniques such as FT-IR, XRD, FE-SEM, HRTEM, EDS, BET, VSM, XPS, DRS and TGA. The new nanocatalyst, Fe3O4@MCM-41-SB-Pd, was used in synthesis of symmetrical and unsymmetrical biaryl compounds via the Suzuki–Miyaura cross-coupling of phenylboronic acid with aryl halides. This catalyst was easily recovered by applying an external magnetic field and reused for several times without significant loss of its catalytic activity. Also the ability of synthesized mesoporous nanocomposites for enzyme immobilization was investigated and results showed that they efficiently immobilized α-amylase enzyme.

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Acknowledgement

Support of this work by Shahid Chamran University of Ahvaz, Iran (Grant No. 1397) is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Shahid Chamran University of Ahvaz, Ahvaz, Iran

    Ameneh Ahmadi, Tahereh Sedaghat & Roya Azadi

  2. Department of Biology, Faculty of Science, Shahid Chamran University of Ahvaz, Ahvaz, Iran

    Hossein Motamedi

  3. Biotechnology and Biological Science Research Center, Shahid Chamran University of Ahvaz, Ahvaz, Iran

    Hossein Motamedi

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  1. Ameneh Ahmadi
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  2. Tahereh Sedaghat
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  3. Roya Azadi
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  4. Hossein Motamedi
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Correspondence to Tahereh Sedaghat.

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Ahmadi, A., Sedaghat, T., Azadi, R. et al. Magnetic Mesoporous Silica Nanocomposite Functionalized with Palladium Schiff Base Complex: Synthesis, Characterization, Catalytic Efficacy in the Suzuki–Miyaura Reaction and α-Amylase Immobilization. Catal Lett 150, 112–126 (2020). https://doi.org/10.1007/s10562-019-02913-5

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