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Novel Biomass-Derived Fe3O4@Pd NPs as Efficient and Sustainable Nanocatalyst for Nitroarene Reduction in Aqueous Media

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Abstract

A novel magnetically recyclable nitrogen-doped Fe3O4@Pd NPs was prepared from the biomass-based materials which was employed as carbon and nitrogen source. The as-prepared catalysts were fully characterized by a variety of physicochemical techniques and were exploited for nitroaromatic hydrogenation with broad scope and excellent chemoselectivity using molecular hydrogen as a reductant. The heterogeneous catalysts can be recovered easily and reused for at least eight recycling reactions without obviously loss of catalytic properties. In addition, using this protocol, the key intermediate of marketed drug Osimertinib could be synthesized easily.

Graphical Abstract

A core-shell nanostructured Pd@nitrogen-containing catalyst exhibited robust catalytic performance in the hydrogenation of nitroarene

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Acknowledgements

Financial support from Science and Technology Plan of Zhejiang Province (No. 2017C31054, 2017C32011), Zhejiang Provincial Natural Science Foundation of China (No. LY17B020005) and the National Natural Science Foundation of China (No. 21302171). We acknowledge the support of the Young and Middle-aged academic team Project of Zhejiang Shuren University.

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Authors and Affiliations

  1. College of Petroleum Chemical Industry, Changzhou University, Changzhou, 213164, China

    Linwei Zhao

  2. College of Biology and Environmental Engineering, Zhejiang Shuren University, Hangzhou, 310015, China

    Kai Zheng, Jianying Tong, Jianzhong Jin & Chao Shen

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  1. Linwei Zhao
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  2. Kai Zheng
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  3. Jianying Tong
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  4. Jianzhong Jin
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Correspondence to Jianzhong Jin or Chao Shen.

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Zhao, L., Zheng, K., Tong, J. et al. Novel Biomass-Derived Fe3O4@Pd NPs as Efficient and Sustainable Nanocatalyst for Nitroarene Reduction in Aqueous Media. Catal Lett 149, 2607–2613 (2019). https://doi.org/10.1007/s10562-019-02829-0

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