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Synthesis of Fe3O4-DOPA-Cu Magnetically Separable Nanocatalyst: A Versatile and Robust Catalyst for an Array of Sustainable Multicomponent Reactions under Microwave Irradiation

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Abstract

Herein, we are reporting a facile route to synthesize magnetically separable copper loaded L-DOPA functionalized magnetite nanoparticles (Fe3O4-DOPA-CuNPs), which are well characterized by FT-IR, PXRD, SEM, EDAX, HRTEM, XPS, TGA and VSM techniques. This single catalyst exhibits excellent catalytic activity towards (i) synthesis of DHPMs via Biginelli reaction (ii) synthesis of imidazoles (iii) synthesis of 2-amino-4H-chromenes (iv) 1,2,3-triazole derivatives by ‘Click reaction’ under microwave irradiation (MWI). Interestingly it can be easily recovered and reused for subsequent cycles for above mentioned four important multicomponent reactions without any significant decrease in its catalytic activity.

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Acknowledgements

Authors are thankful to Materials Research Centre, MNIT Jaipur for providing spectral analysis facilities. M. Kumari acknowledge to Department of Science and technology (DST), India, for providing JRF under INSPIRE fellowship scheme (IF140506). One of the author Y. Jain is grateful to MNIT Jaipur for proving financial assistance. Other authors P. Yadav and H. Laddha are thankful to CSIR for providing JRF.

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Authors and Affiliations

  1. Department of Chemistry, Malaviya National Institute of Technology, Jaipur, 302017, India

    Mitlesh Kumari, Yachana Jain, Priya Yadav, Harshita Laddha & Ragini Gupta

  2. Materials Research Centre, Malaviya National Institute of Technology, Jaipur, 302017, India

    Ragini Gupta

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  1. Mitlesh Kumari
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  2. Yachana Jain
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  3. Priya Yadav
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Correspondence to Ragini Gupta.

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Kumari, M., Jain, Y., Yadav, P. et al. Synthesis of Fe3O4-DOPA-Cu Magnetically Separable Nanocatalyst: A Versatile and Robust Catalyst for an Array of Sustainable Multicomponent Reactions under Microwave Irradiation. Catal Lett 149, 2180–2194 (2019). https://doi.org/10.1007/s10562-019-02794-8

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