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Fabrication of Super-Hydrophobic Titanosilicate Sub-micro Sphere with Enhanced Epoxidation Catalytic Activity

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Abstract

A super-hydrophobic titanosilicate sub-micro sphere was synthesized via coating a layered organo-titanosilicate onto a hydrophobic silica sphere. The obtained materials exhibit enhanced catalytic activity in cyclohexene epoxidation at 30 °C using 30% H2O2 aqueous solution as oxidant.

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Notes

  1. Consumed H2O2 mole amount for CHE oxidation = total mole amount of (7-Oxabicyclo[4.1.0] heptanes + 2-mol Cyclohexen-1-ol + 1,2-Cyclohexanediol) + 2 × the mole amount of 2-Cyclohexen-1-one.

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Acknowledgements

This work was supported by National Natural Science Foundation of China (21271153, 21373181, 21222307, U1402233), Major Research Plan of National Natural Science Foundation of China (91545113), the Fundamental Research Funds for the Central Universities (2014XZZX003-02), Fok Ying Tung Education Foundation (131015), Zhejiang Provincial Natural Science Foundation of China (LQ16B030004), the Research and Development Fund of Zhejiang A & F University (2014FR061) and Zhejiang Provincial Key Laboratory of Chemical Utilization of Forestry Biomass (2017CUFB10).

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Authors and Affiliations

  1. Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou, 310027, Zhejiang, China

    Sha Li, Liping Xiao, Jie Fan & Xiaoming Zheng

  2. Key Laboratory of Chemical Utilization of Forestry Biomass of Zhejiang Province, Zhejiang A & F University, Lin’an, 311300, Zhejiang, China

    Sha Li

  3. Hangzhou First Applied Material Co.,Ltd, Hangzhou, 311300, Zhejiang, China

    Hui Zhou

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  1. Sha Li
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  2. Hui Zhou
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  3. Liping Xiao
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  4. Jie Fan
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  5. Xiaoming Zheng
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Correspondence to Liping Xiao.

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10562_2019_2720_MOESM1_ESM.doc

Supplementary material 1. † Electronic Supplementary Information (ESI) available: FT-IR spectra and catalytic performance. (DOC 1559 KB)

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Li, S., Zhou, H., Xiao, L. et al. Fabrication of Super-Hydrophobic Titanosilicate Sub-micro Sphere with Enhanced Epoxidation Catalytic Activity. Catal Lett 149, 1396–1402 (2019). https://doi.org/10.1007/s10562-019-02720-y

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  • DOI: https://doi.org/10.1007/s10562-019-02720-y

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