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Catalysis Letters

, Volume 149, Issue 3, pp 851–859 | Cite as

Magnetic Anchored CoPt Bimetallic Nanoparticles as Selective Hydrogenation Catalyst for Cinnamaldehyde

  • Tao Yuan
  • Derong Liu
  • Yue Pan
  • Xiaoqin Pu
  • Yongde Xia
  • Jinbo Wang
  • Wei XiongEmail author
Article
  • 157 Downloads

Abstract

Selective hydrogenation reaction of cinnamaldehyde is crucial for its appliction in fine chemical industries. The traditional noble metal catalyst for this reaction is expensive and often involving tedious steps. In this work, the magnetic anchored CoPt/Fe3O4 catalyst is prepared by a simple wet-impregnation method and evaluted as catalyst for selective hydrogenation of cinnamaldehyde. Electrons transfer directly from Co to Pt NPs can enhance H2 dissociation capability in the Co NPs interface, thereby strengthen the overall catalytic performance. Under optimum conditions, the conversion of cinnamaldehyde is 95% with 84% selectivity of cinnamyl alcohol. Furthermore, the magnetic interaction between the outer Co NPs and the Fe3O4 support maintains the stability of cinnamyl alcohol selectivity after repeated tests.

Graphical Abstract

Keywords

CoPt/Fe3O4 NPs Electron transfer Selective hydrogenation Magnetic separation 

Notes

Acknowledgements

The authors are grateful for the financial support from the Basic and Frontier Research Project of Chongqing in China (No. cstc2016jcyjA0139). Moreover, I very much appreciate my tutors for giving many precious suggestions about how to conduct experiments and write article.

Compliance with Ethical Standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

10562_2018_2619_MOESM1_ESM.docx (276 kb)
Supplementary material 1 (DOCX 275 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Tao Yuan
    • 1
  • Derong Liu
    • 1
  • Yue Pan
    • 1
  • Xiaoqin Pu
    • 1
  • Yongde Xia
    • 2
  • Jinbo Wang
    • 1
  • Wei Xiong
    • 1
    Email author
  1. 1.Institute of Chemistry and Chemical EngineeringChongqing University of Science and TechnologyChongqingChina
  2. 2.College of Engineering, Mathematics and Physical SciencesUniversity of ExeterExeterUK

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