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Replication of SMSI via ALD: TiO2 Overcoats Increase Pt-Catalyzed Acrolein Hydrogenation Selectivity

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Abstract

The effects of sub-nanometer atomic layer deposition films of titania and alumina are compared for the acrolein hydrogenation selectivity of Pt/SrTiO3 catalysts. The titania-overcoated catalyst is similar to strong metal-support interaction catalysts formed by high temperature reduction, with a thin titania film on top of the supported Pt nanoparticles and an increase in allyl alcohol selectivity, neither of which are observed for the alumina-overcoated catalyst.

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Acknowledgements

This material is based on work supported as part of the Institute for Atom-efficient Chemical Transformations (IACT), an Energy Frontiers Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. RMK and LAC acknowledge funding from Northwestern University Institute for Catalysis in Energy Processes (ICEP) on Grant No. DOE DE-FG02-03-ER15457. Electron microscopy was performed at the EPIC facility supported by the NU-MRSEC program (NSF DMR-1121262) and at the UIC Research Resources Center supported by the MRI-R2 grant from the National Science Foundation (NSF DMR-0959470). The CleanCat Core facility acknowledges funding from the Department of Energy (DE-FG02-03-ER15457) used for the purchase of the Altamira AMI-200. Metal analysis was performed at the Northwestern University Quantitative Bio-element Imaging Center.

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Authors and Affiliations

  1. Department of Chemistry, Northwestern University, Evanston, IL, 60208, USA

    Robert M. Kennedy, Kenneth R. Poeppelmeier & Peter C. Stair

  2. Department of Materials Science and Engineering, Northwestern University, Evanston, IL, 60208, USA

    Lawrence A. Crosby, Ahmet Gulec & Laurence D. Marks

  3. Chemical Engineering, Louisiana State University, Baton Rouge, LA, 70803, USA

    Kunlun Ding

  4. Energy Systems Division, Argonne National Laboratory, Lemont, IL, 60439, USA

    Christian P. Canlas & Jeffrey W. Elam

  5. Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL, 60439, USA

    Christopher L. Marshall, Kenneth R. Poeppelmeier & Peter C. Stair

Authors
  1. Robert M. Kennedy
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  2. Lawrence A. Crosby
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  3. Kunlun Ding
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  4. Christian P. Canlas
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  9. Kenneth R. Poeppelmeier
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Contributions

Electron microscopy was performed by LAC and AG. Atomic layer deposition of Pt and Al2O3 was performed by CPC (Grace, formerly ANL) and JWE (ANL). Atomic layer deposition of TiO2 was by KD (NU). This manuscript was written with contribution of all authors. All authors have given approval to the final version of the manuscript.

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Correspondence to Peter C. Stair.

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Kennedy, R.M., Crosby, L.A., Ding, K. et al. Replication of SMSI via ALD: TiO2 Overcoats Increase Pt-Catalyzed Acrolein Hydrogenation Selectivity. Catal Lett 148, 2223–2232 (2018). https://doi.org/10.1007/s10562-018-2458-5

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