Reduced Temperature Ammonia Decomposition Using Ni/Zr-Doped Al2O3 Catalyst

  • Suparoek Henpraserttae
  • Sumittra Charojrochkul
  • Wantana Klysubun
  • Luckhana Lawtrakul
  • Pisanu Toochinda
Article
  • 70 Downloads

Abstract

The development of Ni/Zr-doped Al2O3 was achieved to reduce the reaction temperatures in ammonia decomposition by doping Zr into Al2O3 framework. The Ni/Zr-doped Al2O3 exhibits higher H2 yield and NH3 conversion than Ni/γ-Al2O3 in a continuous operation. Partial doping of Zr in Al2O3 framework can increase Ni dispersion, Ni surface area and basic sites of the Ni catalyst. These effects can promote in both dehydrogenation of NH3 and recombination of nitrogen adsorbates in an NH3 decomposition mechanism. The comparison between roles of Zr as a dopant and a promoter for Ni catalyst was also discussed.

Graphical Abstract

Keywords

Ammonia decomposition Hydrogen production Support modification Partial doping of Zr in Al2O3 framework Ni/Zr-doped Al2O3 catalyst 

Notes

Acknowledgements

This work was funded by the National Research University Project of Thailand Office of Higher Education Commission (NRU-15/2559) and Thammasat University Grant (TU-2/23/2558). This work was also supported by National Science and Technology Development Agency Thailand. The authors gratefully acknowledge Mr. Mahinsasa Rathnayake for English proof-reading.

References

  1. 1.
    Choudhary TV, Goodman DW (2002) Catal Today 77:65CrossRefGoogle Scholar
  2. 2.
    Yao LH, Li YX, Zhao J, Ji WJ, Au CT (2010) Catal Today 158:401CrossRefGoogle Scholar
  3. 3.
    Lan R, Irvine JTS, Tao S (2012) Int J Hydr Energy 37:1482CrossRefGoogle Scholar
  4. 4.
    Zamfirescu C, Dincer I (2009) Fuel Process. Technol 90:729CrossRefGoogle Scholar
  5. 5.
    Chiuta S, Everson RC, Neomagus HWJP, van der Gryp P, Bessarabov DG (2013) Int J Hydr Energy 38:14968CrossRefGoogle Scholar
  6. 6.
    Wang W, Herreros JM, Tsolakis A, York APE (2013) Int J Hydr Energy 38:9907CrossRefGoogle Scholar
  7. 7.
    Nakamura I, Fujitani T (2016) Appl Catal A 524:45CrossRefGoogle Scholar
  8. 8.
    Okura K, Okanishi T, Muroyama H, Matsui T, Eguchi K (2015) Appl Catal A 505:77CrossRefGoogle Scholar
  9. 9.
    Zheng W, Zhang J, Ge Q, Xu H, Li W (2008) Appl Catal B 80:98CrossRefGoogle Scholar
  10. 10.
    Choudhary TV, Sivadinarayana C, Goodman DW (2001) Catal Lett 72:197CrossRefGoogle Scholar
  11. 11.
    Liu H, Wang H, Shen J, Sun Y, Liu Z (2008) Catal Today 131:444CrossRefGoogle Scholar
  12. 12.
    Deng Q-F, Zhang H, Hou X-X, Ren T-Z, Yuan Z-Y (2012) Int J Hydr Energy 37:15901CrossRefGoogle Scholar
  13. 13.
    Yin SF, Xu BQ, Zhou XP, Au CT (2004) Appl Catal A 277:1CrossRefGoogle Scholar
  14. 14.
    Yin SF, Xu B-Q, Ng C-F, Au C-T (2004) Appl Catal B 48:237CrossRefGoogle Scholar
  15. 15.
    Yin SF, Xu BQ, Wang SJ, Ng CF, Au CT (2004) Catal Lett 96:113CrossRefGoogle Scholar
  16. 16.
    Yin SF, Xu BQ, Zhu WX, Ng CF, Zhou XP, Au CT (2004) Catal Today 93–95:27CrossRefGoogle Scholar
  17. 17.
    Chen J, Zhu ZH, Wang S, Ma Q, Rudolph V, Lu GQ (2010) Chem Eng J 156:404CrossRefGoogle Scholar
  18. 18.
    Schwarz JA, Contescu C, Contescu A (1995) Chem Rev 95:477CrossRefGoogle Scholar
  19. 19.
    Roy B, Martinez U, Loganathan K, Datye AK, Leclerc CA (2012) Int J Hydr Energy 37:8143CrossRefGoogle Scholar
  20. 20.
    Zhang J, Xu H, Li W (2005) Appl Catal A 296:257CrossRefGoogle Scholar
  21. 21.
    Siriruang C, Charojrochkul S, Toochinda P (2016) Monatsh Chem 147:1143CrossRefGoogle Scholar
  22. 22.
    Ganduglia-Pirovano MV, Hofmann A, Sauer J (2007) Surf Sci Rep 62:219CrossRefGoogle Scholar
  23. 23.
    Duan X, Qian G, Fan C, Zhu Y, Zhou X, Chen D, Yuan W (2012) Surf Sci 606:549CrossRefGoogle Scholar
  24. 24.
    Chellappa AS, Fischer CM, Thomson WJ (2002) Appl Catal A 227:231CrossRefGoogle Scholar
  25. 25.
    Yang X, Wang X, Gao G, Wendurima, Liu E, Shi Q, Zhang J, Han C, Wang J, Lu H, Liu J, Tong M (2013) Int J Hydr Energy 38:13926CrossRefGoogle Scholar
  26. 26.
    Verwey EJW (1935) Z Kristallogr 91:317Google Scholar
  27. 27.
    Moreau S, Gervais M, Douy A (1997) Solid State Ionics 101–103(Part 1):625Google Scholar
  28. 28.
    Cullity BD (1956) Elements of X-ray diffraction. Addison-Wesley Pub. Co., ReadingGoogle Scholar
  29. 29.
    Klysubun W, Sombunchoo P, Deenan W, Kongmark C (2012) J Synchrotron Rad 19:930CrossRefGoogle Scholar
  30. 30.
    Ravel B, Newville M (2005) J Synchrotron Rad 12:537CrossRefGoogle Scholar
  31. 31.
    Seoud A-LA, Abdallah LA (2010) Am J Appl Sci 7:509CrossRefGoogle Scholar
  32. 32.
    Li D, Bancroft GM, Fleet ME, Feng XH, Pan Y (1995) Am Mineral 80:432CrossRefGoogle Scholar
  33. 33.
    Ahuja R, Osorio-Guillen JM, Almeida JSD, Holm B, Ching WY, Johansson B (2004) J Phys Condens Matter 16:2891CrossRefGoogle Scholar
  34. 34.
    Mo S-D, Xu Y-N, Ching W-Y (1997) J Am Ceram Soc 80:1193CrossRefGoogle Scholar
  35. 35.
    Streitz FH, Mintmire JW (1999) Phys Rev B 60:773CrossRefGoogle Scholar
  36. 36.
    Dehmer JL (1972) J Chem Phys 56:4496CrossRefGoogle Scholar
  37. 37.
    Ferrett TA, Lindle DW, Heimann PA, Kerkhoff HG, Becker UE, Shirley DA (1986) Phys Rev A 34:1916CrossRefGoogle Scholar
  38. 38.
    Wang CM, Cargill GS, Chan HM, Harmer MP (2002) J Am Ceram Soc 85:2492CrossRefGoogle Scholar
  39. 39.
    Duan X, Qian G, Zhou X, Sui Z, Chen D, Yuan W (2011) Appl Catal B 101:189CrossRefGoogle Scholar
  40. 40.
    Ganley JC, Thomas FS, Seebauer EG, Masel RI (2004) Catal Lett 96:117CrossRefGoogle Scholar
  41. 41.
    Yin SF, Zhang Q-H, Xu B-Q, Zhu W-X, Ng C-F, Au C-T (2004) J Catal 224:384CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Suparoek Henpraserttae
    • 1
  • Sumittra Charojrochkul
    • 2
  • Wantana Klysubun
    • 3
  • Luckhana Lawtrakul
    • 1
  • Pisanu Toochinda
    • 1
  1. 1.School of Bio-Chemical Engineering and Technology, Sirindhorn International Institute of TechnologyThammasat UniversityPathum ThaniThailand
  2. 2.National Metal and Materials Technology CenterNational Science and Technology Development AgencyPathum ThaniThailand
  3. 3.Synchrotron Light Research InstituteNakhon RatchasimaThailand

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