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Behavior of IrCl3 as a Homogeneous Catalyst on the Oxidation of N-Acetylglucosamine in Acid Medium and Uncatalyzed Reaction in Alkaline Medium with Bromamine-B: Exploration of Kinetic, Mechanistic and Catalytic Chemistry

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Abstract

The experimental rate laws for the oxidation of N-acetylglucosamine with bromamine- B are: − d[BAB]/dt = k/ [BAB]1 [GlcNAc]0.69 [HClO4]−0.76 [IrCl3]0.48  [BSA]−0.33 in acid medium and –d[BAB]/dt = k/ [BAB]1 [GlcNAc]1 [NaOH]0.79 in alkaline medium. The IrCl3 catalyzed reaction is thirteen fold faster than uncatalyzed reaction. Appropriate mechanisms and rate laws were deduced.

Graphical Abstract

The reaction of N-acetylglucosamine with Bromamine-B in acid and alkaline medium is

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Acknowledgements

One of the authors (S D) is gratefully acknowledge the UGC, New Delhi for awarding UGC-BSR Meritorious Scholarship. The Authors are also thankful to Prof. M.A. Pasha of this department for his valuable suggestions on the proposed reaction schemes.

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  1. Department of Post Graduate Studies in Chemistry, Bangalore University, Central College Campus, Bangalore, 560001, India

    Dakshayani Shankarlingaiah &  Puttaswamy

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  1. Dakshayani Shankarlingaiah
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  2. Puttaswamy
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Correspondence to Puttaswamy.

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Shankarlingaiah, D., Puttaswamy Behavior of IrCl3 as a Homogeneous Catalyst on the Oxidation of N-Acetylglucosamine in Acid Medium and Uncatalyzed Reaction in Alkaline Medium with Bromamine-B: Exploration of Kinetic, Mechanistic and Catalytic Chemistry. Catal Lett 148, 424–437 (2018). https://doi.org/10.1007/s10562-017-2244-9

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