Skip to main content

Mixed Oxides Without Added Noble Metals Derived from Layered Double Hydroxides of the Hydrotalcite Type in the Hydrodechlorination Reaction of Trichloroethylene

Abstract

NiMgAl-, CuNiAl- and CuMgAl-layered double hydroxides were prepared and after calcination, they were used to promote the hydrodechlorination of trichloroethylene. The calcined materials were active in the reaction and remained so in the repeated reaction after applying the rehydration-recalcination regeneration protocol. The freshly prepared, the calcined, the used, as well as the regenerated materials were studied by a range of methods (X-ray diffractometry, scanning electron microscopy, energy-dispersive X-ray analysis, BET surface area measurements). These results together with reaction data proved that the calcined layered double hydroxides, even without noble metal additives, acted as occasionally highly active and always highly hydrocarbon-selective catalysts in the hydrodechlorination reaction.

Graphical Abstract

This is a preview of subscription content, access via your institution.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

References

  1. Hochstetter C (1842) J Prakt Chem 27:375–378

    Article  Google Scholar 

  2. Molls SJ, Christy AG, Génin J-MR, Kameda T, Colombo F (2012) Miner Mag 76:1289–1336

    Article  Google Scholar 

  3. Feitknecht W, Gerber M (1942) Helv Chim Acta 25:131–137

    CAS  Article  Google Scholar 

  4. Carrado KA, Kostapapas A, Suib SL (1988) Solid State lonics 26:77–86

    CAS  Article  Google Scholar 

  5. Cavani F, Trifiró F, Vaccari A (1991) Catal Today 11:173–301

    CAS  Article  Google Scholar 

  6. Vaccari A (1998) Catal Today 41:53–71

    CAS  Article  Google Scholar 

  7. Evans DG, Slade RCT (2006) Struct Bond 119:1–87

  8. Miyata S (1980) Clays Clay Miner 28:50–56

    CAS  Article  Google Scholar 

  9. Corma A, Fairness V, Martín-Aranda RM, Frey F (1992) J Catal 134:58–65

    CAS  Article  Google Scholar 

  10. Roelofs JCA, Lensveld DJ, van Dillen AJ, de Jong KP (2001) J Catal 203:184–191

    CAS  Article  Google Scholar 

  11. Xu ZP, Zhang J, Adebajo MO, Zhang H, Zhou C (2011) Appl Clay Sci 53:139–150

    CAS  Article  Google Scholar 

  12. He S, An Z, Wei M, Evans DG, Duan X (2013) Chem Commun 49:5912–5920

    CAS  Article  Google Scholar 

  13. Tessier R, Tichit D, Figueras F, Kervennal J (1995) FR Patent 95 00094

  14. Rao KK, Gravelle M, Valente JS, Figueras F (1998) J Catal 173:115–121

    CAS  Article  Google Scholar 

  15. Ueno S, Yamaguchi K, Yoshida K, Ebitani K, Kaneda K (1998) Chem Commun. doi:10.1039/A707655J

    Google Scholar 

  16. Suzum E, Okamoto M, Ono Y (1990) J Mol Catal 61:283–294

    Article  Google Scholar 

  17. Zhu K, Liu C, Ye X, Wu Y (1998) Appl Catal A 168:365–372

    CAS  Article  Google Scholar 

  18. Choudary BM, Kantam ML, Reddy CRV, Rao KK, Figuéras F (1999) J Mol Catal A 146:279–284

    CAS  Article  Google Scholar 

  19. Choudary BM, Kantam ML, Reddy CRV, Aranganathan S, Santhi PL, Figuéras F (2000) J Mol Catal A 159:411–416

    CAS  Article  Google Scholar 

  20. Mészáros S, Halász J, Kónya Z, Sipos P, Pálinkó I (2013) Appl Clay Sci 80–81:245–248

    Article  Google Scholar 

  21. Morato A, Alonso C, Medina F, Cesteros Y, Salagre P, Sueiras JE, Tichit D, Coq B (2001) Appl Catal B 32:167–179

    CAS  Article  Google Scholar 

  22. Meshesha BT, Chimentão RJ, Medina F, Sueiras JE, Cesteros Y, Salagre P, Figueras F (2009) Appl Catal B 87:70–77

    CAS  Article  Google Scholar 

  23. Barrabes N, Cornado D, Föttinger K, Dafinov A, Llorca J, Medina F, Rupprechter G (2009) J Catal 263:239–246

    CAS  Article  Google Scholar 

  24. Meshesha BT, Barrabés N, Föttinger K, Chimentão RJ, Llorca J, Medina F, Rupprechter G, Sueiras JE (2012) Appl Catal B 117–118:236–245

    Article  Google Scholar 

  25. Feng J-T, Lin Y-J, Evans DG, Duan X, Li D-Q (2009) J Catal 266:351–358

    CAS  Article  Google Scholar 

  26. Wang Y, Wang J, Fan G, Li F (2012) Catal Commun 19:56–60

    Article  Google Scholar 

  27. Wang J, Fan G, Li F (2012) RSC Adv 2:9976–9985

    CAS  Article  Google Scholar 

  28. Lan M, Fan G, Wang Y, Yang L, Li F (2014) J Mater Chem A 2:14682–14689

    CAS  Article  Google Scholar 

  29. Dimotakis ED, Pinnavaia TJ (1990) Inorg Chem 29:2393–2394

    CAS  Article  Google Scholar 

Download references

Acknowledgements

This research was financed by the OTKA NK 106234 and the GINOP-2.3.2-15-2016-00013 grants. All these supports are highly appreciated.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to István Pálinkó.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 2303 KB)

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Török, J., Halász, J., Kónya, Z. et al. Mixed Oxides Without Added Noble Metals Derived from Layered Double Hydroxides of the Hydrotalcite Type in the Hydrodechlorination Reaction of Trichloroethylene. Catal Lett 147, 2910–2919 (2017). https://doi.org/10.1007/s10562-017-2203-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-017-2203-5

Keywords

  • Calcined layered double hydroxides
  • Catalytic hydrodechlorination of trichlorethylene
  • Recycling study
  • Instrumental characterisation