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MMZNiY-Catalyzed Tsuji–Trost Type of Reaction: A Selective Mono/Bis Allylation of Dicarbonyl Compounds

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Abstract

An alternative method to Pd-catalyzed Tsuji–Trost reaction is developed and it provides a simpler route for the selective synthesis of a broad range of mono-/bis-allylated and cinnamylated 1,3-dicarbonyl compounds using MMZNiY catalyst at room temperature. Product selectivity can be controlled by the proper choice of catalyst. The catalyst was also well characterized by SEM, TEM, HRTEM, EDAX and X-ray analysis. Other advantages of catalyst like its ease of preparation, functional tolerance and its reusability are also highlighted.

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Acknowledgements

Authors thank The Principal and The Management of ANJA College, Sivakasi for providing necessary facilities as well as the University Grants Commission, New Delhi [F. No. 41-334/2012 (SR)] for its financial support.

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Authors and Affiliations

  1. Centre for Research and Post-graduate Studies in Chemistry, Ayya Nadar Janaki Ammal College (Autonomous), Sivakasi, Tamil Nadu, 626 124, India

    Samuthirarajan Senthilkumar, Cheirmakani Thangapriya, Raman Alagumurugayee & Mayilvasagam Kumarraja

Authors
  1. Samuthirarajan Senthilkumar
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  2. Cheirmakani Thangapriya
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  3. Raman Alagumurugayee
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  4. Mayilvasagam Kumarraja
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Correspondence to Mayilvasagam Kumarraja.

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Senthilkumar, S., Thangapriya, C., Alagumurugayee, R. et al. MMZNiY-Catalyzed Tsuji–Trost Type of Reaction: A Selective Mono/Bis Allylation of Dicarbonyl Compounds. Catal Lett 147, 2755–2763 (2017). https://doi.org/10.1007/s10562-017-2185-3

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  • DOI: https://doi.org/10.1007/s10562-017-2185-3

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