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Fabrication of Supported Pd–Ir Mesocrystal Catalyst for Hydrogenation of 2-Ethylanthraquinone

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Abstract

Pd–Ir mesocrystals with rough surface and highly branched structure were synthesized through a facile co-reduction method. The morphology evolution shows the mesocrystals were formed by oriented attachment of nanoparticles, and abundant defects sites as well as synergetic effect between building units were formed during mesocrystals oriented attachment process. Therefore, the supported Pd–Ir mesocrystals show a significant enhancement in catalytic performance in hydrogenation of 2-ethylanthraquinone compared with conventional Pd–Ir nanoparticles. The high activity can be ascribed to high densities of defect sites in Pd–Ir MCs catalyst, which facilitated H2 activation. In addition, the geometric effect of Pd–Ir MCs catalyst was responsible for inhibiting further hydrogenation of eAQH2 to undesired consecutive byproducts.

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Acknowledgements

This work was supported by the National Key Research and Development Program of China (No. 2016YFB0301601) as well as the Fundamental Research Funds for the Central Universities (JD1616).

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Authors and Affiliations

  1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, 15 Bei San Huan East Road, Box 98, Beijing, 100029, China

    Runrun Hong, Yufei He, Chenglin Miao, Junting Feng & Dianqing Li

  2. Beijing Engineering Center for Hierarchical Catalysts, Beijing University of Chemical Technology, 15 Bei San Huan East Road, Box 98, Beijing, 100029, China

    Runrun Hong, Yufei He, Chenglin Miao, Junting Feng & Dianqing Li

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  1. Runrun Hong
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  2. Yufei He
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  3. Chenglin Miao
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  4. Junting Feng
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  5. Dianqing Li
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Correspondence to Yufei He or Dianqing Li.

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Hong, R., He, Y., Miao, C. et al. Fabrication of Supported Pd–Ir Mesocrystal Catalyst for Hydrogenation of 2-Ethylanthraquinone. Catal Lett 147, 1802–1810 (2017). https://doi.org/10.1007/s10562-017-2076-7

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  • DOI: https://doi.org/10.1007/s10562-017-2076-7

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