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Novel Preparation of Titania-Modified CMK-3 Nanostructured Material as Support for Ir Catalyst Applied in Hydrodenitrogenation of Indole

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Abstract

Iridium catalyst was prepared using a novel titanium oxide-CMK-3 support synthesized as a replica of Ti-SBA-15. The catalyst was applied in the hydrodenitrogenation of indole. The activity was compared with an iridium catalyst supported over a grafted titanium-CMK-3. Structural and textural characterization of the catalysts was performed by means of N2 adsorption, XRD, UV–Vis–DRS, Raman spectroscopy, XPS, TEM and H2 Chemisorption. Ir-Ti-CMK-3 was the most active catalyst for the hydrodenitrogenation reaction at mild conditions. Titanium oxide contained in carbon ordered mesoporous CMK-3 promotes a very good anchorage of iridium metallic clusters in the carbon framework reaching high active site distribution and more stable nanoclusters.

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Acknowledgements

Brenda C. Ledesma, Juliana M. Juárez, Verónica A. Valles, Oscar A. Anunziata and Andrea R. Beltramone, NANOTEC, CONICET, National Technological University, Cordoba Faculty, Maestro Lopez and Cruz Roja, Argentina. We acknowledge the financial support of CONICET Argentina, PIP CONICET 11220120100218CO. 2014–2017.

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Authors and Affiliations

  1. Centro de Investigación en Nanociencia y Nanotecnología (NANOTEC), Facultad Regional Córdoba, Universidad Tecnológica Nacional, Maestro López y Cruz Roja Argentina, 5016, Córdoba, Argentina

    Brenda C. Ledesma, Juliana M. Juárez, Verónica A. Valles, Oscar A. Anunziata & Andrea R. Beltramone

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  1. Brenda C. Ledesma
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  2. Juliana M. Juárez
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  3. Verónica A. Valles
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  4. Oscar A. Anunziata
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  5. Andrea R. Beltramone
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Correspondence to Andrea R. Beltramone.

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Ledesma, B.C., Juárez, J.M., Valles, V.A. et al. Novel Preparation of Titania-Modified CMK-3 Nanostructured Material as Support for Ir Catalyst Applied in Hydrodenitrogenation of Indole. Catal Lett 147, 1029–1039 (2017). https://doi.org/10.1007/s10562-017-2005-9

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  • DOI: https://doi.org/10.1007/s10562-017-2005-9

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