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Oxidative Dehydrogenation of 1-Butene to 1,3-Butadiene over a Multicomponent Bismuth Molybdate Catalyst: Influence of C3–C4 Hydrocarbons

Abstract

The influence of light hydrocarbons, such as n-butane, isobutane, propylene, cis- and trans-2-butenes, and isobutene on the oxidative dehydrogenation of 1-butene to 1,3-butadiene over BiMoKNiCoFePOx/SiO2 catalyst has been studied using a gas flow reactor. The inhibition effect of the listed hydrocarbons on the target reaction increased in the order of n-butane ~ isobutane < propylene < 2-butenes < isobutene. In addition, in contrast to 1-butene, isobutene has shown significant contribution to coke formation. It was suggested, that the coke formation and therefore the rate of the catalyst regeneration exercise a significant influence on the efficiency of 1-butene transformation into 1,3-butadiene in the concurrent presence of other hydrocarbons.

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Acknowledgements

This work was supported by Russian Academy of Sciences and Federal Agency of Scientific Organizations (project V.44.2.7).

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Correspondence to Vladimir I. Sobolev or Konstantin Yu. Koltunov.

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Sobolev, V.I., Koltunov, K.Y. & Zenkovets, G.A. Oxidative Dehydrogenation of 1-Butene to 1,3-Butadiene over a Multicomponent Bismuth Molybdate Catalyst: Influence of C3–C4 Hydrocarbons. Catal Lett 147, 310–317 (2017). https://doi.org/10.1007/s10562-016-1947-7

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Keywords

  • Oxidative dehydrogenation
  • Multicomponent bismuth molybdate
  • 1-Butene
  • 1,3-Butadiene
  • Concurrent reactions