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Studies on Structural Changes and Catalytic Activity of Y-zeolite Composites of 1,3-disulfoimidazolium trifluoroacetate Ionic Liquid (IL) for Three Component Synthesis of 3,4-dihydropyrimidinones

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Abstract

This report describes the development of six acidic composites of Y-zeolite with 1,3-disulfoimidazolium trifluoroacetate [Dsim][CF3COO] ionic liquid (IL) and displays the gradual increase of acidic IL mediated dealumination within zeolite framework with increasing loading in Powder XRD and IR studies. The structural changes of modified framework of zeolite were analyzed by SEM-EDX, TEM, TGA, BET and UV–Vis techniques. Out of the six composites, the more acidic [Dsim][CF3COO]/NaY = 20% (e) composite was evaluated as heterogeneous catalyst for multicomponent synthesis of 3,4-dihydropyrimidinones (DHPMs) under neat condition at various temperature.

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Acknowledgements

The authors are thankful to Sophisticated Analytical Instrumentation Centre, Tezpur University for analyses of various samples for this work and also acknowledge University Grant Commission, India for granting Junior Research Fellowship (NF-OBC) to P. Gogoi.

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Authors and Affiliations

  1. Department of Chemical Sciences, Tezpur University, Napaam, 784028, Tezpur, Assam, India

    Pinky Gogoi, Arup Kumar Dutta & Ruli Borah

Authors
  1. Pinky Gogoi
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  2. Arup Kumar Dutta
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  3. Ruli Borah
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Corresponding author

Correspondence to Ruli Borah.

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Gogoi, P., Dutta, A.K. & Borah, R. Studies on Structural Changes and Catalytic Activity of Y-zeolite Composites of 1,3-disulfoimidazolium trifluoroacetate Ionic Liquid (IL) for Three Component Synthesis of 3,4-dihydropyrimidinones. Catal Lett 147, 674–685 (2017). https://doi.org/10.1007/s10562-016-1922-3

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  • DOI: https://doi.org/10.1007/s10562-016-1922-3

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