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ZnS@g-C3N4 Composite Photocatalysts: In Situ Synthesis and Enhanced Visible-Light Photocatalytic Activity

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Abstract

ZnS@g-C3N4 composite photocatalysts were synthesized by an in situ thermal polycondensation process under an inert atmosphere. The physicochemical properties of the ZnS@g-C3N4 composite photocatalysts were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), UV–vis diffuse reflectance spectroscopy (UV–vis DRS), and photoluminescence (PL) spectroscopy. The characterization results displayed fine ZnS nanoparticles adhered to the surface of g-C3N4 nanosheets, and the presence of ZnS nanoparticles caused the split and exfoliation of g-C3N4 nanosheets. The ZnS@g-C3N4 composite photocatalysts exhibited the apparent visible-light absorption and the weakened recombination of photogenerated electron/hole pairs. The evaluation on photocatalytic degradation of rhodamine B (RhB) indicated the ZnS@g-C3N4 composite photocatalysts possessed large adsorption capacity and superior visible-light induced activity. Based on the trapping experiments of active species, the photocatalysis mechanism of the ZnS@g-C3N4 composite photocatalysts was also discussed.

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References

  1. Nocera DG (2009) Chem Soc Rev 38:13

    Article  CAS  Google Scholar 

  2. Zhang HJ, Chen GH, Bahnemann DW (2009) J Mater Chem 19:5089

    Article  CAS  Google Scholar 

  3. Sovacool BK (2012) Energy Environ Sci 5:9157

    Article  Google Scholar 

  4. Shen YF (2015) J Mater Chem A 3:13114

    Article  CAS  Google Scholar 

  5. Li X, Yu JG, Jaroniec M (2016) Chem Soc Rev 45:2603

    Article  CAS  Google Scholar 

  6. Ansari SA, Khan MM, Ansaric MO, Cho MH (2016) New J Chem 40:3000

    Article  CAS  Google Scholar 

  7. Li Y, Xu H, Ouyang SX, Ye JH (2016) Phys Chem Chem Phys 18:7563

    Article  CAS  Google Scholar 

  8. Ueno K, Oshikiri T, Misawa H (2016) ChemPhysChem 17:199

    Article  CAS  Google Scholar 

  9. An CH, Wang ST, Sun YG, Zhang QH, Zhang J, Wang CY, Fang JY (2016) J Mater Chem A 4:4336

    Article  CAS  Google Scholar 

  10. Dong GP, Zhang YH, Pan QW, Qiu JR (2014) J Photochem Photobio C 20:33

    Article  CAS  Google Scholar 

  11. Cao SW, Yu JG (2014) J Phys Chem Lett 5:2101

    Article  CAS  Google Scholar 

  12. Yin SM, Han JY, Zhou TH, Xu R (2015) Catal Sci Technol 5:5048

    Article  CAS  Google Scholar 

  13. Patnaik S, Martha S, Acharya S, Parida KM (2016) Inorg Chem Front 3:336

    Article  CAS  Google Scholar 

  14. Patnaik S, Martha S, Parida KM (2016) RSC Adv 6:46929

    Article  CAS  Google Scholar 

  15. Martha S, Nashim A, Parida KM (2013) J Mater Chem A 1:7816

    Article  CAS  Google Scholar 

  16. Samanta S, Martha S, Parida K (2014) ChemCatChem 6:1453

    CAS  Google Scholar 

  17. Panyab S, Parida KM (2015) Phys Chem Chem Phys 17:8070

    Article  Google Scholar 

  18. Nayak S, Mohapatra L, Parida K (2015) J Mater Chem A 3:18622

    Article  CAS  Google Scholar 

  19. Dong XP, Cheng FX (2015) J Mater Chem A 3:23642

    Article  CAS  Google Scholar 

  20. Tong JC, Zhang L, Li F, Li MM, Cao SK (2015) Phys Chem Chem Phys 17:23532

    Article  CAS  Google Scholar 

  21. Bu YY, Chen ZW, Xie T, Li WB, Ao JP (2016) RSC Adv 6:47813

    Article  CAS  Google Scholar 

  22. Huang ZJ, Li FB, Chen BF, Yuan GQ (2016) ChemSusChem 9:478

    Article  CAS  Google Scholar 

  23. Wang YY, Ibad MF, Kosslick H, Harloff J, Beweries T, Radnik J, Schulz A, Tschierlei S, Lochbrunner S, Guo XY (2015) Microporous Mesoporous Mater 211:182

    Article  CAS  Google Scholar 

  24. Zhang YW, Liu JH, Wu G, Chen W (2012) Nanoscale 4:5300

    Article  CAS  Google Scholar 

  25. Wei HT, Zhang Q, Zhang YC, Yang ZJ, Zhu AP, Dionysiou DD (2016) Appl Catal A 521:9

    Article  CAS  Google Scholar 

  26. Hong JD, Xia XY, Wang YS, Xu R (2012) J Mater Chem 22:15006

    Article  CAS  Google Scholar 

  27. Tay QL, Kanhere P, Ng CF, Chen S, Chakraborty S, Huan ACH, Sum TC, Ahuja R, Chen Z (2015) Chem Mater 27:4930

    Article  CAS  Google Scholar 

  28. Liao GZ, Chen S, Quan X, Yu HT, Zhao HM (2012) J Mater Chem 22:2721

    Article  CAS  Google Scholar 

  29. Dong F, Zhao ZW, Xiong T, Ni ZL, Zhang WD, Sun YJ, Ho WK (2013) ACS Appl Mater Interfaces 5:11392

    Article  CAS  Google Scholar 

  30. Huang LY, Xu H, Li YP, Li HM, Cheng XN, Xia JX, Xu YG, Cai GB (2013) Dalton Trans 42:8606

    Article  CAS  Google Scholar 

  31. Chen J, Shen SH, Guo PH, Wang M, Wu P, Wang XX, Guo LJ (2014) Appl Catal B 152–153:335

    Article  Google Scholar 

  32. Wang J, Guo P, Guo QS, Jönssona PG, Zhao Z (2014) CrystEngComm 16:4485

    Article  CAS  Google Scholar 

  33. Li JH, Liu YL, Li HM, Chen C (2016) J Photochem Photobio A 317:151

    Article  CAS  Google Scholar 

  34. Shan WJ, Hu Y, Bai ZG, Zheng MM, Wei CH (2016) Appl Catal B 188:1

    Article  CAS  Google Scholar 

  35. Ge L, Han CC, Liu J, Li YF (2011) Appl Catal A 409:215

    Article  Google Scholar 

  36. Dong F, Sun YJ, Wu LW, Fu M, Wu ZB (2012) Catal Sci Technol 2:1332

    Article  CAS  Google Scholar 

  37. Zhang GG, Zhang JS, Zhang MW, Wang XC (2012) J Mater Chem 22:8083

    Article  CAS  Google Scholar 

  38. Lv HL, Ji GB, Yang ZH, Liu YS, Zhang XM, Liu W, Zhang HQ (2015) J Colloid Inter Sci 450:381

    Article  CAS  Google Scholar 

  39. Jia FZ, Yao ZP, Jiang ZH (2012) Int J Hydrog Energy 37:3048

    Article  CAS  Google Scholar 

  40. Yue S, Wei BW, Guo XD, Yang SX, Wang LY, He J (2016) Catal Comm 76:37

    Article  CAS  Google Scholar 

  41. Zheng Y, Jiao Yan, Zhu YH, Li LH, Han Y, Chen Y, Du AJ, Jaroniec M, Qiao SZ (2014) Nature Comm 5:3783

    Google Scholar 

  42. Li KX, Zeng ZX, Yan LS, Huo MX, Guo YH, Luo SL, Luo XB (2016) Appl Catal B 187:269

    Article  CAS  Google Scholar 

  43. Li JX, Dai WL, Wu GJ, Guan NJ, Li LD (2015) Catal Commun 65:24

    Article  CAS  Google Scholar 

  44. Shi L, Liang L, Wang FX, Liu MS, Liang T, Chen KL, Sun JMRSCA (2015) 5:63264

  45. Moniz SJA, Shevlin SA, Martin DJ, Guo ZX, Tang JW (2015) Energy Environ Sci 8:731

    Article  CAS  Google Scholar 

  46. Wang XW, Li YN, Wang MR, Li WJ, Chen MF, Zhao Y (2014) New J Chem 38:4182

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by Shanghai Ocean University (Project: A2-0203-00-100529).

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Authors and Affiliations

  1. Department of Chemistry, College of Food Science and Technology, Shanghai Ocean University, Shanghai, 201306, China

    Bin Xue, Hai-Yun Jiang, Tao Sun & Fang Mao

Authors
  1. Bin Xue
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  2. Hai-Yun Jiang
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  3. Tao Sun
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  4. Fang Mao
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Correspondence to Bin Xue.

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Xue, B., Jiang, HY., Sun, T. et al. ZnS@g-C3N4 Composite Photocatalysts: In Situ Synthesis and Enhanced Visible-Light Photocatalytic Activity. Catal Lett 146, 2185–2192 (2016). https://doi.org/10.1007/s10562-016-1844-0

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