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Copper Tetrasulfophthalocyanine Intercalated Hydrotalcite as an Efficient Bifunctional Catalyst for the Baeyer–Villiger Oxidation

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Abstract

A heterogeneous bifunctional hybrid catalyst originated from copper tetrasulfophthalocyanine (CuPcTs) and hydrotalcite for Baeyer–Villiger (B-V) oxidation has been prepared and characterized. XRD, FTIR, DR UV-Vis and SEM characterization indicate that CuPcTs molecule has been successfully intercalated into the layer of ZnAl hydrotalcite. And the synthesized hybrid exhibited excellent catalytic activity in the B-V oxidation for various ketones under mild conditions. Its bifunctional role in the reaction through O2/benzaldehyde has been discussed and verified by controlled experiments. The study indicates that the designed catalyst not only catalyzes the oxidation of benzaldehyde to perbenzoic acid, but also accelerates the transformation of ketone to lactone or ester.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Grant No. 21403018), Top-notch Academic Programs Project of Jiangsu Higher Education Institutions, and Prospective Joint Research Project on the Industry, Education and Research of Jiangsu Province (BY2015027-16).

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Authors and Affiliations

  1. Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Changzhou University, Changzhou, 213164, China

    Weiyou Zhou, Yong Chen, Junfeng Qian, Fu’an Sun, Mingyang He & Qun Chen

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  1. Weiyou Zhou
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  2. Yong Chen
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  3. Junfeng Qian
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  4. Fu’an Sun
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  5. Mingyang He
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Correspondence to Mingyang He.

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Zhou, W., Chen, Y., Qian, J. et al. Copper Tetrasulfophthalocyanine Intercalated Hydrotalcite as an Efficient Bifunctional Catalyst for the Baeyer–Villiger Oxidation. Catal Lett 146, 2157–2164 (2016). https://doi.org/10.1007/s10562-016-1823-5

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  • DOI: https://doi.org/10.1007/s10562-016-1823-5

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