Co–Rh Nanoparticles for the Hydrogenation of Carbon Monoxide: Catalytic Performance Towards Alcohol Production and Ambient Pressure X-Ray Photoelectron Spectroscopy Study
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5 nm Co–Rh bimetallic nanoparticles with narrow size distributions and three different atomic compositions (2, 10, and 16 % Rh) were synthesized using a colloidal method. The bimetallic nanoparticles were loaded into mesoporous silica support MCF-17 and utilized in the catalytic hydrogenation of CO (Fischer–Tropsch synthesis). As compared to the pure 5 nm Co/MCF-17 catalyst, the bimetallic Co–Rh catalysts showed a similar activity while enhancing the selectivity towards alcohols, as evidenced by an increased ratio of alcohol to hydrocarbon products. Furthermore, larger alcohols such as propanol were formed with the addition of Rh, which is not observed with the pure Co/MCF-17 catalyst. In situ synchrotron based Ambient Pressure X-ray Photoelectron Spectroscopy studies on the Co–Rh samples revealed that Rh is segregated to the surface of the nanoparticles under reaction conditions, which plays an important role in altering the selectivity towards alcohol production. An optimum surface Rh concentration exists at ~9 at.%, where a fivefold enhancement in the alcohol-to-hydrocarbon ratio was achieved.
KeywordsFischer–Tropsch synthesis Ambient pressure X-ray photoelectron spectroscopy Co–Rh bimetallic nanoparticles Alcohol production
This work was supported by the Director, Office of Science, Office of Basic Energy Sciences, Materials Sciences and Engineering Division, U.S. Department of Energy, under Contract DE-AC02-05CH11231, through the Chemical and Mechanical Properties of Surfaces, Interfaces and Nanostructures program (FWP KC3101). The AP-XPS measurements were conducted on beamline 9.3.2 at The Advanced Light Source, which is supported, by the Director, Office of Science, Office of Basic Energy Sciences, U.S. Department of Energy, under Contract No. DE-AC02-05CH11231.