Skip to main content
SpringerLink
Log in

Environmentally Benign Oxidations of Alkenes and Alcohols to Corresponding Aldehydes over Anchored Phosphotungstates: Effect of Supports as Well as Oxidants

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Series of catalysts comprising of parent phosphotungstate (PW12) and mono lacunary phosphotungstate (PW11) anchored to different mesoporous materials (MCM-41 and MCM-48) were prepared. Environmentally benign oxidation of alkenes and alcohols were carried out with H2O2 and molecular oxygen as oxidants. The influence of different parameters on the conversion as well as the selectivity was investigated. Comparative study was ascertained over anchored parent, lacunary phosphotungstates as active species and the supports. The kinetic and thermodynamic studies were correlated with the effect of support as well as active species. Moreover, the catalysts could be recovered and reused four times without significant loss in their activity and selectivity.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Scheme 1
Scheme 2

Similar content being viewed by others

References

  1. McGrath DV, Grubbs RH, Ziller JW (1991) J Am Chem Soc 113:3611–3613

    Article  CAS  Google Scholar 

  2. Okuhara T, Mizuno N, Misono M (1996) Adv Catal 41:113–252

    CAS  Google Scholar 

  3. Okuhara T (2002) Chem Rev 102:3641–3666

    Article  CAS  Google Scholar 

  4. Maksimchuk NV, Kovalenko KA, Arzumanov SS, Chesalov YA, Melgunov MS, Stepanov AG, Fedin VP, Kholdeeva OA (2010) Inorg Chem 49:2920–2930

    Article  CAS  Google Scholar 

  5. Tamiolakis I, Lykakis IN, Katsoulidis AP, Malliakas CD, Armatas GS (2012) J Mater Chem 22:6919–6927

    Article  CAS  Google Scholar 

  6. Meng LY, Zhai SR, Li S, Zhai B, An QD, Song XW (2014) Eur J Inorg Chem 14:2337–2344

    Article  Google Scholar 

  7. Skliri E, Lykakis IN, Armatas GS (2014) RSC Adv 4:8402–8409

    Article  CAS  Google Scholar 

  8. Wang B, Zhang J, Zou X, Dong H, Yao P (2015) Chem Eng J 260:172–177

    Article  CAS  Google Scholar 

  9. Patel A, Singh S (2013) Ind Eng Chem Res 52:10896–10904

    Article  CAS  Google Scholar 

  10. Massart R, Contant R, Fruchart JM, Clabrini JP, Fournier M (1977) Inorg Chem 16:2916–2921

    Article  CAS  Google Scholar 

  11. Dolbecq A, Dumas E, Mayer CR, Mialane P (2010) Chem Rev 110:6009–6048

    Article  CAS  Google Scholar 

  12. Weng Z, Wang J, Jian X (2008) Catal Commun 9:1688–1691

    Article  CAS  Google Scholar 

  13. Li H, Xiang QY, Huan L, Bo F, Yan PZ, Yin YY, Wen ZW, Shan HZ (2011) Sci China Chem 54:769–773

    Google Scholar 

  14. Ding Y, Zhao W (2011) J Mol Catal A: Chem 337:45–51

    Article  CAS  Google Scholar 

  15. Hill CL, Kholdeeva OA, (2013) Liquid phase oxidation via heterogeneous catalysis (eds.), Clerici MG, Kholdeeva OA, Ch 6, Wiley, New York

  16. Mizuno N, Kamata K, Uchida S, Yamaguchi K (2009) Modern heterogeneous oxidation catalysis, Ch. 6 (eds), Mizuno N, Wiley, New York

  17. Lefebvre F (1992) J Chem Soc Chem Commun 756–757

  18. Kozhevnikov IV, Kloetstra KR, Sinnema A, Zandbergen HW, van Bekkum H (1996) J Mol Catal A: Chem 114:287–298

    Article  CAS  Google Scholar 

  19. Zhao H, Zeng L, Li Y, Liu C, Hou B, Wu D, Feng N, Zheng A, Xie X, Su S, Yu N (2013) MicroporousMesoporous Mater 172:67–76

    Article  CAS  Google Scholar 

  20. Granadeiro CM, Barbosa ADS, Silva P, Paz FAA, Saini VK, Pires J, de Castro B, Balula SS, Silva LC (2013) Appl Catal A: Gen 453:316–326

    Article  CAS  Google Scholar 

  21. Hua L, Chen J, Chen C, Zhu W, Yu Y, Zhang R, Guo L, Song B, Gan H, Hou Z (2014) New J Chem 38:3953–3959

    Article  CAS  Google Scholar 

  22. Li K, Wang J, Zou Y, Song X, Gao H, Zhu W, Zhang W, Yu J, Jia M (2014) Appl Catal A: Gen 482:84–91

    Article  CAS  Google Scholar 

  23. Shringarpure PA, Patel A (2010) Dalton Trans 39:2615–2621

    Article  CAS  Google Scholar 

  24. Shringarpure PA, Patel A (2011) Chem Eng J 173:612–619

    Article  CAS  Google Scholar 

  25. Shringarpure PA, Patel A (2011) Ind Eng Chem Res 50:9069–9076

    Article  CAS  Google Scholar 

  26. Patel A, Singh S (2014) Microporous Mesoporous Mater 195:240–249

    Article  CAS  Google Scholar 

  27. Singh S, Patel A (2014) J Cleaner Prod 72:46–56

    Article  CAS  Google Scholar 

  28. Singh S, Patel A (2015) Fuel 159:720–727

    Article  CAS  Google Scholar 

  29. Narkhede N, Singh S, Patel A (2015) Green Chem 17:89–107

    Article  CAS  Google Scholar 

  30. Bond GC (1974) Heterogeneous catalysis: principles and applications. In: Oxford chemistry series, p. 49 (Chapter 3)

  31. Fernandes SA, Cardoso AL, da Silva MJ (2012) Fuel Process Technol 96:98–103

    Article  CAS  Google Scholar 

  32. Khan MI, Swenson LS (2013) New and future developments in catalysis, hybrid materials, composites, and organocatalysts. In: Steven LS (ed), Elsevier, Amsterdam, Ch-2

  33. Baker LCW, Glick DC (1998) Chem Rev 98:3–49

    Article  CAS  Google Scholar 

  34. Guo Y, Yang Y, Hu C, Guo C, Wang E, Zou Y, Feng S (2002) J Mater Chem 12:3046–3052

    Article  CAS  Google Scholar 

  35. Yoshida A, Hikichi S, Mizuno N (2007) J Organomet Chem 692:455–459

    Article  CAS  Google Scholar 

  36. Mizuno N (2008) Mechanisms in homogeneous and heterogeneous epoxidation catalysts. In: Oyama ST (ed), Ch-4. Elseiver, New York

  37. Pathan S, Patel S (2014) Chem Eng J 243:183–191

    Article  CAS  Google Scholar 

  38. Sheldon RA, Walau M, Arends IWEC, Schuchurdt U (1998) Acc Chem Res 31:485–493

    Article  CAS  Google Scholar 

  39. Xu G, Xia QH, Lu XH, Zhang Q, Zhan HJ (2007) J Mol Catal A: Chem 266:180–187

    Article  CAS  Google Scholar 

  40. Wang F, Ueda W (2008) Appl Catal A: Gen 346:155–163

    Article  CAS  Google Scholar 

  41. Weng ZH, Wang JY, Jian XG (2007) Chin Chem Lett 18:936–938

    Article  CAS  Google Scholar 

  42. Gharah N, Chakraborty S, Mukherjee AK, Bhattacharyya R (2009) Inorg Chim Acta 362:1089–1100

    Article  CAS  Google Scholar 

  43. Singh S, Narkhede N, Patel A (2015) RSC Adv 5:36270–36278

    Article  CAS  Google Scholar 

Download references

Acknowledgments

We are thankful to Department of Science and technology (DST), Project No. SR/S5/GC-01/2009, New Delhi, for the financial support. One of the authors Ms. Sukriti Singh is thankful to the same for the grant of research fellowship.

Author information

Authors and Affiliations

  1. Polyoxometalates and Catalysis Laboratory, Department of Chemistry, Faculty of Science, The M. S. University of Baroda, Vadodara, Gujarat, 390002, India

    Sukriti Singh & Anjali Patel

Authors
  1. Sukriti Singh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Anjali Patel
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Anjali Patel.

Electronic Supplementary Material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 912 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Singh, S., Patel, A. Environmentally Benign Oxidations of Alkenes and Alcohols to Corresponding Aldehydes over Anchored Phosphotungstates: Effect of Supports as Well as Oxidants. Catal Lett 146, 1059–1072 (2016). https://doi.org/10.1007/s10562-016-1732-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-016-1732-7

Keywords

Search

Navigation