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Heteropolyacid Bisalt of N-octyl Ethoxylated Octadecylamine: An Efficient and Reusable Catalyst for Carboxylic Acid-Free Hydration of α-Pinene

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Abstract

A series of heteropoly acid bisalts of N-octyl ethoxylated octadecylamine with high acid strength and excellent emulsifying capacity have been prepared via the partial replacement of protons in neat phosphotungstic acid. These ionic liquids exhibit good activity and selectivity in the hydration of α-pinene, even in the absence of a co-catalyst such as chloroacetic acid. The “excellent emulsifying capacity at the reaction temperature and the liquid–liquid separation at room temperature” for the obtained organic heteropolyacid bisalts catalysts enable their easy recovery and reusability, as demonstrated by a six-run recycling test.

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Acknowledgments

The financial support provided for this research by the National Science Foundation of China (31470595, 31270615 and 21106074), Opening Foundation of Beijing National Laboratory for Molecular Sciences (20140141), and “The Taishan Scholar Program of Shandong” is gratefully acknowledged.

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Authors and Affiliations

  1. State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China

    Bing Yuan, Hua Zhong, Peifeng Liu, Xiaofan Liu, Congxia Xie & Fengli Yu

  2. College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China

    Shitao Yu

  3. Beijing National Laboratory for Molecular Sciences, Beijing, 100190, China

    Jianling Zhang

Authors
  1. Bing Yuan
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  2. Hua Zhong
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  3. Peifeng Liu
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  4. Xiaofan Liu
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  5. Congxia Xie
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  6. Fengli Yu
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  7. Shitao Yu
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  8. Jianling Zhang
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Corresponding author

Correspondence to Congxia Xie.

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Yuan, B., Zhong, H., Liu, P. et al. Heteropolyacid Bisalt of N-octyl Ethoxylated Octadecylamine: An Efficient and Reusable Catalyst for Carboxylic Acid-Free Hydration of α-Pinene. Catal Lett 146, 929–936 (2016). https://doi.org/10.1007/s10562-016-1709-6

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  • DOI: https://doi.org/10.1007/s10562-016-1709-6

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