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Catalysis Letters

, Volume 146, Issue 2, pp 493–498 | Cite as

Asymmetric Biginelli Reaction Catalyzed by Silicon, Titanium and Aluminum Oxides

  • Olga V. Fedorova
  • Yulia A. TitovaEmail author
  • Alexey Yu. Vigorov
  • Maria S. Toporova
  • Olga A. Alisienok
  • Anna N. Murashkevich
  • Victor P. Krasnov
  • Gennady L. Rusinov
  • Valery N. Charushin
Article

Abstract

The asymmetric Biginelli reaction was investigated in the presence of N-[(2S,4R)-4-hydroxyprolyl]-(S)-1-phenylethylamine as chiral inducer and silicon, titanium or aluminum oxides (individual and mixed, bulk and nanosized) as heterogeneous catalysts. It has been shown that all studied oxides improve chemo- and stereoselectivity of the Biginelli reaction.

Graphical Abstract

Keywords

Asymmetric catalysis The Biginelli reaction Condensation Nanoparticles Chemoselectivity Heterogeneous catalysis 

Notes

Acknowledgments

This study was financially supported by the Russian Foundation for Basic Research (Projects Nos. 13-03-12188-ofi_m and 14-03-31357-mol_a).

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • Olga V. Fedorova
    • 1
    • 3
  • Yulia A. Titova
    • 1
    • 3
    Email author
  • Alexey Yu. Vigorov
    • 1
  • Maria S. Toporova
    • 1
  • Olga A. Alisienok
    • 2
  • Anna N. Murashkevich
    • 2
  • Victor P. Krasnov
    • 1
  • Gennady L. Rusinov
    • 1
    • 3
  • Valery N. Charushin
    • 1
    • 3
  1. 1.Postovsky Institute of Organic Synthesis, Ural BranchRussian Academy of SciencesYekaterinburgRussia
  2. 2.Belarusian State Technical UniversityMinskBelarus
  3. 3.Ural Federal University Named after the First President of Russia B.N. YeltsinYekaterinburgRussia

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