Abstract
Uniform rutile SnO2 nanoparticles with small size (ca. 3 nm) were highly dispersed on both sides of GO sheets through electrostatic interactions, giving pseudo-homogeneous catalysts of SnO2/GO nanocomposites. The SnO2-decorated GO nanocomposites, especially, SnO2 (15 wt%)/GO was highly efficient and reusable in Baeyer–Villiger oxidation of ketones with H2O2.
Graphical Abstract
SnO2/GO nanocomposites, where uniform SnO2 nanoparticles were tightly gripped on both sides of GO sheets by surface oxygenated functional groups through electrostatic interaction, have proved to be a versatile, efficient and reusable catalyst for the BV oxidation of ketones with H2O2.
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Acknowledgments
The project was financially supported by the National Natural Science Foundation of China (Grant No. 21476069), the Scientific Research Fund of Hunan Provincial Education Department (13B072), the Program for Excellent Talents in Hunan Normal University (ET14103), the Hunan Provincial Innovation Foundation for Postgraduate (CX2013B209) and the Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province.
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Zheng, W., Tan, R., Luo, X. et al. SnO2 Nanoparticle-Decorated Graphene Oxide Sheets Efficiently Catalyze Baeyer–Villiger Oxidation with H2O2 . Catal Lett 146, 281–290 (2016). https://doi.org/10.1007/s10562-015-1639-8
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DOI: https://doi.org/10.1007/s10562-015-1639-8