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On Synthesis and Characterization of Sulfated Alumina–Zirconia Catalysts for Isobutene Alkylation

Abstract

The porous structure and surface acid–base properties of sulfated zirconia, alumina and alumina–zirconia applied in isobutylene alkylation were characterized using a variety of physico-chemical methods. Catalytic activity was related to catalyst physico-chemical properties.

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References

  1. 1.

    Olah GA, Martinez E, Torok B, Prakash GKS (1999) Catal Lett 61:105–110

    CAS  Article  Google Scholar 

  2. 2.

    Aschauer S, Schilder L, Korth W, Fritschi S, Jess A (2011) Catal Lett 141:1405–1419

    CAS  Article  Google Scholar 

  3. 3.

    Esteves PM, Araujo CL, Horta BAC, Alvarez LJ, Zicovich-Wilson CM, Ramirez-Solis A (2005) J Phys Chem B 109:12946–12955

    CAS  Article  Google Scholar 

  4. 4.

    Kolesov SV, Tsadkin MA, Badikova AD, Rakhmanov RR, Kudasheva FKh, Gimaev RN (2002) Chem Tech Fuels Oils 4:15–17

    Google Scholar 

  5. 5.

    Lopez Nieto JM (1999) Anais Assoc Brasil de Quimica 48:126–129

    CAS  Google Scholar 

  6. 6.

    Patrilyak KI, Patrilyak LK, Voloshina YG, Manza IA, Konovalov SV (2011) Theor Exp Chem 47:205–214

    CAS  Article  Google Scholar 

  7. 7.

    Nakamura I, Fan L, Ishida S, Fujimoto K (1997) Sekiyu Gakkaishi 40:61–64

    CAS  Article  Google Scholar 

  8. 8.

    Koklin AE, Chan VMKh, Bogdan VI (2014) Russ J Phys Chem B 8:991–998

    CAS  Article  Google Scholar 

  9. 9.

    Zhang Q, Jiao Q-Z, Min E-Z (2005) Gaodeng Xuexiao Huaxue Xuebao 26:1130–1132

    CAS  Google Scholar 

  10. 10.

    Corma A, Martinez A, Martinez C (1994) J Catal 149:52–60

    CAS  Article  Google Scholar 

  11. 11.

    Lavrenov AV, Perelevskii EV, Finevich VP (2003) Russ J Appl Chem 76:570–578

    Article  Google Scholar 

  12. 12.

    Lavrenov AV, Finevich VP, Kirilov VL (2003) Neftekhimia 43:61–365

    Google Scholar 

  13. 13.

    Takase M, Zhang M, Feng W, Chen Y, Zhao T, Cobbina SJ, Yang L, Wu X (2014) Energy Conv Manag 80:117–125

    CAS  Article  Google Scholar 

  14. 14.

    Zhao J, Xie J, Au C-T, Yin S-F (2014) RSC Adv 4:6159–6164

    CAS  Article  Google Scholar 

  15. 15.

    Gregg SJ, Sing KSW (1967) Adsorption, surface and porosity. Academic Press, London

    Google Scholar 

  16. 16.

    Nechiporenko AP, Vlasov EA, Kudryashova AA (1986) Russ J Appl Chem 3:689–692

    Google Scholar 

  17. 17.

    Corma A, Martinez A, Martinez C (1996) Appl Catal A 144:249–268

    CAS  Article  Google Scholar 

  18. 18.

    Xiao X, Tierney J, Wender I (1999) Appl Catal A 183:209–219

    CAS  Article  Google Scholar 

  19. 19.

    Sychov MM, Zakharova NV, Mjakin SV (2013) Ceram Int 39:6821–6826

    CAS  Article  Google Scholar 

  20. 20.

    Vasilivea IV, Mjakin SV, Rylova EV, Korsakov VG (2002) Russ J Phys Chem 76:84–89

    Google Scholar 

Download references

Acknowledgments

This work was executed at the Laboratory of Catalytic Technologies at St. Petersburg State Institute of Technology supported by the mega-grant of the Government of the Russian Federation.

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Correspondence to D. Yu. Murzin.

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Vlasov, E.A., Myakin, S.V., Sychov, M.M. et al. On Synthesis and Characterization of Sulfated Alumina–Zirconia Catalysts for Isobutene Alkylation. Catal Lett 145, 1651–1659 (2015). https://doi.org/10.1007/s10562-015-1575-7

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Keywords

  • Alumina
  • Zirconia
  • Porosity
  • Surface acid–base properties
  • Isobutylene alkylation