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Synergistic Effect of Nickel Species and γ-Alumina Added to HZSM-5 on the Methanol to Aromatics

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Abstract

Ni/HZSM-5 catalysts with γ-alumina were prepared by the sol–gel method. At first, reaction performances were investigated over the HZSM-5 catalysts with and without γ-alumina. Then, reaction evaluations were conducted over the Ni/HZSM (different loading amounts of nickel species were investigated) catalysts with and without γ-alumina. The addition of nickel species and γ-alumina increased the total acidity of the catalysts. Furthermore, the introduction of γ-alumina increased the amount of mesopores in the catalysts. Nickel species were much more stable with the presence of γ-alumina. Both nickel species and γ-alumina contributed the aromatization of methanol.

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Acknowledgments

The authors acknowledge the financial support provided by the National 973 Program of China (No. 2012CB215006) and the Livelihood Program of Qingdao, China (No. 13-1-3-126-nsh).

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Authors and Affiliations

  1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao, 266580, China

    Hongqiang Ji, Qiang Zhang, Bin Wang, Chunyi Li & Honghong Shan

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  1. Hongqiang Ji
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  2. Qiang Zhang
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  3. Bin Wang
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  4. Chunyi Li
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  5. Honghong Shan
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Correspondence to Qiang Zhang or Chunyi Li.

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Ji, H., Zhang, Q., Wang, B. et al. Synergistic Effect of Nickel Species and γ-Alumina Added to HZSM-5 on the Methanol to Aromatics. Catal Lett 144, 1860–1867 (2014). https://doi.org/10.1007/s10562-014-1348-8

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  • DOI: https://doi.org/10.1007/s10562-014-1348-8

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