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Catalysis Letters

, Volume 144, Issue 8, pp 1399–1406 | Cite as

Cellulose Sulfuric Acid Catalyzed Esterification of Biodiesel Derived Raw Glycerol to Medium Chain Triglyceride: The Dual Advantage

  • Mehulkumar L. Savaliya
  • Bharatkumar Z. DholakiyaEmail author
Article

Abstract

Biodiesel derived raw glycerol represent a copious and inexpensive source which can be used as raw material for a variety of value added products such as 1,3-propanediol, poly hydroxyalkanoate, hydrogen, epichlorohydrin and also lactic acid. So, this work was investigated to study chemical conversion of biodiesel derived raw glycerol and lauric acid to triglycerides of lauric acid via esterification reaction over cellulose sulfuric acid as an efficient, biodegradable and recyclable solid acid catalyst. Synthesized catalyst was characterized by fourier transform infra-red spectroscopy (FT-IR) as well as BET surface area analysis. While, synthesized triglyceride of lauric acid was fittingly characterized by FT-IR as well as 1H and 13C Nuclear magnetic resonance spectroscopic techniques.

Graphical Abstract

Keywords

Glycerol Cellulose sulfuric acid (CSA) Epichlorohydrin Biodiesel Esterification 

Notes

Acknowledgments

The authors are very much thankful to the Department of Applied Chemistry, Sardar Vallabhbhai National Institute of Technology (SVNIT), Surat for providing laboratory facilities and financial support for the course of this work. For characterization, we are thankful to Mr. Avtar Singh, SAIF, Punjab University, Chandigarh and Mr. M. H. Malani as well as Mr. M. Rathod from Department of Applied Chemistry, Sardar Vallabhbhai National Institute of Technology (SVNIT), Surat, India are gratefully acknowledged.

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • Mehulkumar L. Savaliya
    • 1
  • Bharatkumar Z. Dholakiya
    • 1
    Email author
  1. 1.Department of Applied ChemistryS.V. National Institute of TechnologySuratIndia

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