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Catalytic Degradation of LDPE and PP over MCM-49 Based Micro–Mesoporous Composites

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Abstract

Micro–mesoporous composites were prepared by post-treatment of MCM-49, and applied to degrade low-density polyethylene (LDPE) and polypropylene. It was found that LDPE degradation mainly occurred on the external surface of MCM-49. The highest activity was achieved over the sample with large external surface area and relatively high acid site concentration. The main products of LDPE degradation were liquefied petroleum gas and gasoline range hydrocarbons, and the product selectivity depended on the acid site concentration.

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Acknowledgments

This work was supported by National Key Project of Fundamental Research (Grant No. 2009CB623501), National Natural Science Foundation of China (Nos. 21006104, 21203190, 21376235).

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Authors and Affiliations

  1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China

    Ningning Gao, Sujuan Xie, Shenglin Liu, Jie An, Xiangxue Zhu, Linyan Hu, Huijuan Wei, Xiujie Li & Longya Xu

  2. University of Chinese Academy of Sciences, Beijing, 100049, China

    Ningning Gao & Huijuan Wei

  3. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China

    Linyan Hu & Longya Xu

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  1. Ningning Gao
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  2. Sujuan Xie
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  5. Xiangxue Zhu
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Correspondence to Sujuan Xie or Longya Xu.

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Gao, N., Xie, S., Liu, S. et al. Catalytic Degradation of LDPE and PP over MCM-49 Based Micro–Mesoporous Composites. Catal Lett 144, 1296–1304 (2014). https://doi.org/10.1007/s10562-014-1205-9

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  • DOI: https://doi.org/10.1007/s10562-014-1205-9

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