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Effects of Alkali Halide Salts on Hydrocarboxylation of Styrene Catalyzed by Water-Soluble Palladium Phosphine Complexes

Catalysis Letters volume 143, pages289–297(2013)Cite this article

Abstract

Hydrocarboxylation of styrene catalyzed by water-soluble Pd-TPPTS complexes was investigated. The reaction conditions, including reaction pressure, temperature, time and etc. have a significant influence on the catalytic performance. It was found that the yield of total acids and the selectivity towards 3-phenylpropionic acid were enhanced by adding a suitable amount of alkali metal halide salts. In addition, the reaction mechanism and the role of alkali metal halide salts in the reaction were discussed on the basis of the characterization of 1H NMR and 31P NMR.

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Acknowledgments

The authors are grateful for the support from the National Natural Science Foundation of China (U1179302) and One Hundred Person Project of the Chinese Academy of Sciences.

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Affiliations

  1. Xinjiang Technical Institute of Physics and Chemistry, The Chinese Academy of Sciences, Urumqi, 830011, People’s Republic of China
    • Zhenhong He
    • , Yanping Luo
    • , Liang Zhou
    • , Yuanfeng Liu
    •  & Wumanjiang Eli
  2. Graduate University of the Chinese Academy of Sciences, Beijing, 100049, People’s Republic of China
    • Zhenhong He
    • , Yanping Luo
    • , Liang Zhou
    •  & Yuanfeng Liu
  3. Key Laboratory for Advanced Materials, Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai, 200237, People’s Republic of China
    • Zhenshan Hou
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Correspondence to Zhenshan Hou.

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He, Z., Hou, Z., Luo, Y. et al. Effects of Alkali Halide Salts on Hydrocarboxylation of Styrene Catalyzed by Water-Soluble Palladium Phosphine Complexes. Catal Lett 143, 289–297 (2013). https://doi.org/10.1007/s10562-013-0961-2

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Keywords

  • Aqueous two-phase system
  • Hydrocarboxylation
  • Palladium-phosphine complexes
  • Alkali metal halide