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Oxidation and Reduction of Various Substrates Over a Pd(II) Containing Post-Synthesis Metal Organic Framework

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Abstract

A palladium containing metal-organic framework (MOF) compound has been synthesized from MOF, (Zn4O)3(BDC–NH2)3(BTB)4 through Schiff base condensation reaction and complexation of Pd(II). Pd–MOF was found to be an effective heterogeneous catalyst for the oxidation and hydrogenation of various substrates under mild reaction conditions. This catalytic method is highly active and shape selective.

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Acknowledgments

This work was supported by a National Research Foundation of Korea Grant funded by the Korean Government (2012-003212) and Inha University Research Grant.

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Authors and Affiliations

  1. Department of Chemical Engineering, Inha University, Incheon, 402-751, Korea

    Shahin Hossain, Myung-Jong Jin, Ji-hoon Park, Qian Yingjie & Da-Ae Yang

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  1. Shahin Hossain
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  2. Myung-Jong Jin
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  3. Ji-hoon Park
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  4. Qian Yingjie
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  5. Da-Ae Yang
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Correspondence to Myung-Jong Jin.

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Hossain, S., Jin, MJ., Park, Jh. et al. Oxidation and Reduction of Various Substrates Over a Pd(II) Containing Post-Synthesis Metal Organic Framework. Catal Lett 143, 122–125 (2013). https://doi.org/10.1007/s10562-012-0943-9

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  • DOI: https://doi.org/10.1007/s10562-012-0943-9

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