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Effect of Thermal Ageing on the Nature of Iron Species in Fe-BEA

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Abstract

The adsorption of NH3 and NO over fresh and thermally treated Fe-BEA catalysts were studied using in situ DRIFT spectroscopy to follow the evolution of different iron species before and after thermal treatment. Fe-BEA samples were prepared and thermally treated in air at 700 °C for 12, 24 and 48 h, and at 800 and 900 °C for 48 h. Compared to the fresh sample, the NH3 adsorption experiments indicate dealumination of the zeolite and iron oxide particle growth for the aged samples. Furthermore, the NO adsorption experiments show distinct absorption peaks which are assigned to isolated iron species, iron clusters and larger iron oxide particles. The thermally treated samples show migration of isolated iron species from the zeolite pores forming iron oxide particles. Further ageing results in a continuous migration and formation of larger iron oxide particles located on the external surface of the zeolite.

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Acknowledgments

This work has been performed within the FFI program (Proj. No. 32900-1), which is financially supported by the Swedish Energy Agency and partly within the Competence Centre for Catalysis, which is hosted by Chalmers University of Technology and financially supported by the Swedish Energy Agency and the member companies AB Volvo, Volvo Car Corporation AB, Scania CV AB, Haldor Topsøe A/S, and ECAPS AB. Financial support from Knut and Alice Wallenberg Foundation, Dnr KAW 2005.0055, is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Applied Surface Chemistry, Competence Centre for Catalysis, Chalmers University of Technology, 412 96, Göteborg, Sweden

    Soran Shwan, Emma Catherine Adams & Magnus Skoglundh

  2. Volvo Group Trucks Technology, 40508, Gothenburg, Sweden

    Jonas Jansson

Authors
  1. Soran Shwan
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  2. Emma Catherine Adams
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  3. Jonas Jansson
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  4. Magnus Skoglundh
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Correspondence to Magnus Skoglundh.

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Shwan, S., Adams, E.C., Jansson, J. et al. Effect of Thermal Ageing on the Nature of Iron Species in Fe-BEA. Catal Lett 143, 43–48 (2013). https://doi.org/10.1007/s10562-012-0940-z

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  • DOI: https://doi.org/10.1007/s10562-012-0940-z

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