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Partial Oxidation of Methane with the Catalysis of Palladium(II) and Molybdovanadophosphoric Acid Using Molecular Oxygen as the Oxidant

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Abstract

With the catalysis of K2PdCl4 and H5PMo10V2O40 in CF3COOH, methane can be oxidized into CH3COOH and CF3COOCH3 using molecular oxygen as the oxidant at a low temperature. H5PMo10V2O40 is a reversible oxidant that allows to retain Pd(II) in CF3COOH and thus to complete a two-step catalytic cycle of oxidation of methane by molecular oxygen; in addition, it can catalytically oxidize methane into CH3COOH and CF3COOCH3.

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Acknowledgments

This work was supported by the National Natural Sciences Foundation of China (Grant No. 20776013), Beijing Natural Science Foundation (Grant No. 2102034) and the Special Fund of Basic Research in Central Universities (Grant No. JD1107).

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Authors and Affiliations

  1. Department of Environmental Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029, People’s Republic of China

    Jiongliang Yuan, Lu Liu & Lanlan Wang

  2. Department of Experimental Teaching, Tianjin University of Traditional Chinese Medicine, and Tianjin Key Laboratory of Chemistry and Analysis of Chinese Materia Medica, Tianjin, 300193, People’s Republic of China

    Cunjiang Hao

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  1. Jiongliang Yuan
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  2. Lu Liu
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  3. Lanlan Wang
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  4. Cunjiang Hao
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Correspondence to Jiongliang Yuan.

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Yuan, J., Liu, L., Wang, L. et al. Partial Oxidation of Methane with the Catalysis of Palladium(II) and Molybdovanadophosphoric Acid Using Molecular Oxygen as the Oxidant. Catal Lett 143, 126–129 (2013). https://doi.org/10.1007/s10562-012-0931-0

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  • DOI: https://doi.org/10.1007/s10562-012-0931-0

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