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From Gas to Liquid Phase Sulfidation: An IR Spectroscopy Study

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Abstract

A side by side characterization of gas and liquid phase activation of a CoMo/Al2O3 hydrodesulfurization (HDS) catalyst is reported using thiophene HDS as a test reaction and CO adsorption monitored by infrared spectroscopy. The liquid phase sulfidation (high pressure, dimethyldisulfide) leads to the formation of CoMoS sites with higher intrinsic activity compared to the gas phase (H2S/H2).

Graphical Abstract

As compared to the classical gas phase (H2S/H2), the liquid phase sulfidation (high pressure, feed, dimethyldisulfide) changes drastically the spectrum of CO adsorbed on the CoMo/Al2O3: the band attributed to CO in interaction with CoMoS sites is downward shifted (−17 cm−1) while its intensity is decreased

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References

  1. Labruyere F, Dufresne P, Lacroix M, Breysse M (1998) Catal Today 43:111–116

    Article  CAS  Google Scholar 

  2. Glasson C, Geantet C, Lacroix M, Labruyere F, Dufresne P (2002) J Catal 212:76–85

    Article  CAS  Google Scholar 

  3. Berhault G, Mehta A, Pavel AC, Yang JZ, Rendon L, Yacaman MJ, Araiza LC, Moller AD, Chianelli RR (2001) J Catal 198:9–19

    Article  CAS  Google Scholar 

  4. H. Hallie, Oil Gas J. 80 (1982) 69

  5. van Gestel J, Leglise J, Duchet JC (1994) J Catal 145:429–436

    Article  Google Scholar 

  6. Kooyman PJ, Buglass JG, Reinhoudt HR, van Langeveld AD, Hensen EJM, Zandbergen HW, van Veen JAR (2002) J Phys Chem B 106:11795–11799

    Article  CAS  Google Scholar 

  7. Dugulan AI, Hensen EJM, van Veen JAR (2008) Catal Today 130:126–134

    Article  CAS  Google Scholar 

  8. Dugulan AI, Craje MWJ, Kearley GJ (2004) J Catal 222:281–284

    Article  CAS  Google Scholar 

  9. Koizumi N, Yamazaki M, Hatanaka S, Yamada M (1997) Catal Today 39:33–44

    Article  CAS  Google Scholar 

  10. Oliviero L, Mariey L, Lelias MA, Aiello S, van Gestel J, Mauge F (2010) Catal Lett 135:62–67

    Article  CAS  Google Scholar 

  11. Texier S, Berhault G, Pérot G, Harlé V, Diehl F (2004) J Catal 223:404–418

    Article  CAS  Google Scholar 

  12. Qian WH, Yamada S, Ishihara A, Ichinoseki M, Kabe T (2001) Sekiyu Gakkaishi 44:225–231

    Article  CAS  Google Scholar 

  13. Silvy RP, Grange P, Delannay F, Delmon B (1989) Applied Catalysis 46:113–129

    Article  CAS  Google Scholar 

  14. Welch JG, Poyner P, Skelly RF (1994) Oil Gas J 92:56

    CAS  Google Scholar 

  15. Chianelli RR, Berhault G (1999) Catal Today 53:357–366

    Article  CAS  Google Scholar 

  16. Vissers JPR, Debeer VHJ, Prins R (1987) J Chem Soc-Faraday Trans I(83):2145–2155

    Article  Google Scholar 

  17. Vissers JPR, Scheffer B, Debeer VHJ, Moulijn JA, Prins R (1987) J Catal 105:277–284

    Article  CAS  Google Scholar 

  18. Vissers JPR, Mercx FPM, Bouwens S, Debeer VHJ, Prins R (1988) J Catal 114:291–302

    Article  CAS  Google Scholar 

  19. Shuxian Z, Hall WK, Ertl G, Knozinger H (1986) J Catal 100:167–175

    Article  Google Scholar 

  20. Peri JB (1982) J Phys Chem 86:1615–1622

    Article  CAS  Google Scholar 

  21. Bachelier J, Tilliette MJ, Cornac M, Duchet JC, Lavalley JC, Cornet D (1984) Bull Soc Chim Belg 93:743

    Article  CAS  Google Scholar 

  22. Mauge F, Lavalley JC (1992) J Catal 137:69–76

    Article  CAS  Google Scholar 

  23. Mauge F, Vallet A, Bachelier J, Duchet JC, Lavalley JC (1996) J Catal 162:88–95

    Article  CAS  Google Scholar 

  24. Delgado E, Fuentes GA, Hermann C, Kunzmann G, Knozinger H (1984) Bull Soc Chim Belg 93:735–742

    Article  CAS  Google Scholar 

  25. Vogelaar BM, Steiner P, van Langeveld AD, Eijsbouts S, Moulijn JA (2003) Appl Catal A-Gen 251:85–92

    Article  CAS  Google Scholar 

  26. Lelias MA, Kooyman PJ, Mariey L, Oliviero L, Travert A, van Gestel J, van Veen JAR, Mauge F (2009) J Catal 267:14–23

    Article  CAS  Google Scholar 

  27. Glasson C, Geantet C, Lacroix M, Labruyère F, Dufresne P (1998) Catal Today 45:341–346

    Article  CAS  Google Scholar 

  28. Laperdrix E, Sahibed-dine A, Costentin G, Saur O, Bensitel M, Nédez C, Mohamed Saad AB, Lavalley JC (2000) Appl Catal B 26:71–80

    Article  CAS  Google Scholar 

  29. Pieplu A, Saur O, Lavalley J-C, Pijolat M, Legendre O (1996) J Catal 159:394–400

    Article  CAS  Google Scholar 

  30. Elst L, Eijsbouts S, van Langeveld AD, Moulijn JA (2000) J Catal 196:95–103

    Article  CAS  Google Scholar 

  31. Vogelaar BM, Steiner P, van der Zijden TF, van Langeveld AD, Eijsbouts S, Moulijn JA (2007) Appl Catal A-Gen 318:28–36

    Article  CAS  Google Scholar 

  32. Vogelaar BM, Kagami N, van der Zijden TF, van Langeveld AD, Eijsbouts S, Moulijn JA (2009) J Mol Catal A-Chem 309:79–88

    Article  CAS  Google Scholar 

  33. Lange JP, Gutsze A, Allgeier J, Karge HG (1988) Applied Catalysis 45:345–356

    Article  CAS  Google Scholar 

  34. Karge HG, Nießen W, Bludau H (1996) Appl Catal A 146:339–349

    Article  CAS  Google Scholar 

  35. McLellan GD, Howe RF, Parker LM, Bibby DM (1986) J Catal 99:486–491

    Article  CAS  Google Scholar 

  36. Cerqueira HS, Ayrault P, Datka J, Guisnet M (2000) Microporous Mesoporous Mater 38:197–205

    Article  CAS  Google Scholar 

  37. Palumbo L, Bonino F, Beato P, Bjorgen M, Zecchina A, Bordiga S (2008) J Phys Chem C 112:9710–9716

    Article  CAS  Google Scholar 

  38. Li C, Stair PC (1997) Catal Today 33:353–360

    Article  CAS  Google Scholar 

  39. Datka J, Sarbak Z, Eischens RP (1994) J Catal 145:544–550

    Article  CAS  Google Scholar 

  40. Trombetta M, Busca G, Rossini SA, Piccoli V, Cornaro U (1997) J Catal 168:334–348

    Article  CAS  Google Scholar 

  41. Can F, Travert A, Ruaux V, Gilson JP, Maugé F, Hu R, Wormsbecher RF (2007) J Catal 249:79–92

    Article  CAS  Google Scholar 

  42. Travert A, Dujardin C, Mauge F, Veilly E, Cristol S, Paul JF, Payen E (2006) J Phys Chem B 110:1261–1270

    Article  CAS  Google Scholar 

  43. Dujardin C, Lelias MA, van Gestel J, Travert A, Duchet JC, Mauge F (2007) Appl Catal A-Gen 322:46–57

    Article  CAS  Google Scholar 

  44. Hadjiivanov KI, Vayssilov GN, Advances in Catalysis, Vol 47, Academic Press Inc, San Diego, pp 307–511

  45. Lelias MA, Le Guludec E, Mariey L, van Gestel J, Travert A, Oliviero L, Mauge F (2010) Catal Today 150:179–185

    Article  CAS  Google Scholar 

  46. Lelias MA, van Gestel J, Mauge F, van Veen JAR (2008) Catal Today 130:109–116

    Article  CAS  Google Scholar 

  47. Chen W (2009) PhD Thesis, University of Caen, Caen

  48. Aegerter PA, Quigley WWC, Simpson GJ, Ziegler DD, Logan JW, McCrea KR, Glazier S, Bussell ME (1996) J Catal 164:109–121

    Article  CAS  Google Scholar 

  49. Wu WC, Wu ZL, Feng ZC, Ying PL, Li C (2004) Phys Chem Chem Phys 6:5596–5602

    Article  CAS  Google Scholar 

  50. Kelty SP, Berhault G, Chianelli RR (2007) Appl Catal A-Gen 322:9–15

    Article  CAS  Google Scholar 

  51. Travert A, Dujardin C, Mauge F, Cristol S, Paul JF, Payen E, Bougeard D (2001) Catal Today 70:255–269

    Article  CAS  Google Scholar 

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Acknowledgments

Total France and ANRT are acknowledged for the PhD Grant of E. Le Guludec. The authors thank Arnaud Travert and Jacob van Gestel for fruitful discussions. They also thank Christophe Geantet and Chantal Lorentz for the elemental analysis.

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Authors and Affiliations

  1. Laboratoire Catalyse et Spectrochimie, ENSICAEN, Université de Caen, CNRS, 6 bd du Maréchal Juin, 14050, Caen, France

    Erwan Le Guludec, Laetitia Oliviero, Jean Pierre Gilson & Françoise Maugé

  2. Total Research Center Feluy, Zone industrielle C, 7181, Feluy, Belgium

    Erwan Le Guludec, Michaël Rebeilleau, Valentina De Grandi & Sander van Donk

Authors
  1. Erwan Le Guludec
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  2. Laetitia Oliviero
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  3. Jean Pierre Gilson
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  4. Françoise Maugé
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  5. Michaël Rebeilleau
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  6. Valentina De Grandi
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Correspondence to Laetitia Oliviero.

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Le Guludec, E., Oliviero, L., Gilson, J.P. et al. From Gas to Liquid Phase Sulfidation: An IR Spectroscopy Study. Catal Lett 142, 736–743 (2012). https://doi.org/10.1007/s10562-012-0813-5

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  • DOI: https://doi.org/10.1007/s10562-012-0813-5

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