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In Situ FT-IR Study of Diesel Hydrocarbon Oxidation Over Pt/Al2O3 Catalyst

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Abstract

The catalytic performance of Pt/Al2O3 for the total oxidation of a hydrocarbon mixture of n-decane and 1-methylnaphthalene was investigated by using in situ FT-IR spectroscopy. Although carbonate and/or carboxylate species were mainly detected under steady-state conditions, the formation of an acrylate species during the initial stage of the reaction was observed under transient conditions. Based on a comparison of the reaction and formation behavior of the acrylate species and CO2 as a gaseous product, it was proposed that the total oxidation of the hydrocarbon mixture proceeds via the formation of an acrylate species as a reaction intermediate.

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Acknowledgments

This work has been supported by a project of the New Energy and Industrial Technology Development Organization (NEDO) under the sponsorship of Ministry of Economy, Trade and Industry (METI) of Japan: “Rare Metal Substitute Materials Development Project”.

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Authors and Affiliations

  1. Ceramics Research Laboratory, Nagoya Institute of Technology, 10-6-29 Asahigaoka, Tajimi, Gifu, 507-0071, Japan

    Masaaki Haneda & Masakuni Ozawa

  2. Research Center for New Fuels and Vehicle Technology, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki, 305-8565, Japan

    Motoi Sasaki & Hideaki Hamada

Authors
  1. Masaaki Haneda
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  2. Motoi Sasaki
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  3. Hideaki Hamada
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  4. Masakuni Ozawa
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Correspondence to Masaaki Haneda.

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Haneda, M., Sasaki, M., Hamada, H. et al. In Situ FT-IR Study of Diesel Hydrocarbon Oxidation Over Pt/Al2O3 Catalyst. Catal Lett 141, 1262–1267 (2011). https://doi.org/10.1007/s10562-011-0661-8

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  • DOI: https://doi.org/10.1007/s10562-011-0661-8

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