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An Efficient Recyclable Polymer Supported Copper(II) Catalyst for C–N Bond Formation by N-Arylation

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Abstract

Polymer supported Cu(II) catalyst was prepared, characterized and employed for the N-arylation and amination reaction of N–H heterocycles with aryl halides as well as arylboronic acids to afford the corresponding coupled products in good to excellent yields. This catalyst can be used several times with consistent catalytic activity.

Graphical Abstract

R1 = H, Me, OMe, COMe, NO2; R2 = H, Me, OMe, Cl, F, CF3, NO2.

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Acknowledgments

We thank the Department of chemistry, University of Calcutta, for providing us the instrumental support. We gratefully acknowledge DST, New Delhi, for award of grant under its FIST program to the Department of Chemistry, University of Kalyani. SMI acknowledge the following agencies for funding: DST, CSIR and UGC, New Delhi, India.

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Authors and Affiliations

  1. Department of Chemistry, University of Kalyani, Nadia, Kalyani, 741235, West Bengal, India

    Manirul Islam, Sanchita Mondal, Paramita Mondal, Anupam Singha Roy, Manir Mobarok, Sumantra Paul, Noor Salam & Dildar Hossain

  2. Department of Chemistry, B.S. College, Canning, Canning, S-24 PGS, West Bengal, India

    Kazi Tuhina

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  1. Manirul Islam
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  2. Sanchita Mondal
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  3. Paramita Mondal
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  4. Anupam Singha Roy
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  5. Kazi Tuhina
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  6. Manir Mobarok
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  7. Sumantra Paul
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  8. Noor Salam
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  9. Dildar Hossain
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Correspondence to Manirul Islam.

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Islam, M., Mondal, S., Mondal, P. et al. An Efficient Recyclable Polymer Supported Copper(II) Catalyst for C–N Bond Formation by N-Arylation. Catal Lett 141, 1171–1181 (2011). https://doi.org/10.1007/s10562-011-0606-2

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  • DOI: https://doi.org/10.1007/s10562-011-0606-2

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