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An Efficient and Eco-Friendly Nanocrystalline Zinc Oxide Catalyst for One-Pot, Three Component Synthesis of New Ferrocenyl Aminophosphonic Esters Under Solvent-Free Condition

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Abstract

An eco-friendly catalytic amount (10 mol%) of nanocrystalline ZnO has been explored in the synthesis of new series of ferrocenyl aminophosphonic esters by a three-component reaction of ferrocene carbaldehyde, an amine, and a dialkyl phosphate. The nano ZnO catalyzed the selective synthesis of ferrocenyl aminophosphonates and no intermediate formation of either an imines or α-hydroxy phosphonate were observed. This is one of the fundamental aspects in green chemistry for simple experimental and product isolation protocol.

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Acknowledgments

We thank the Shiraz University Research Council, and the Iran National Science Foundation (Grant No. 87040564) for financial support.

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  1. Department of Chemistry, Shiraz University, Shiraz, 71454, Islamic Republic of Iran

    Mona Hosseini-Sarvari

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  1. Mona Hosseini-Sarvari
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Correspondence to Mona Hosseini-Sarvari.

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Hosseini-Sarvari, M. An Efficient and Eco-Friendly Nanocrystalline Zinc Oxide Catalyst for One-Pot, Three Component Synthesis of New Ferrocenyl Aminophosphonic Esters Under Solvent-Free Condition. Catal Lett 141, 347–355 (2011). https://doi.org/10.1007/s10562-010-0489-7

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