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Palladium-Catalyzed Carbonylative Cyclization of β-Bromo-α,β-Unsaturated Ketones Leading to Alkylidenefuranones

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Abstract

β-Bromo-α,β-unsaturated ketones are carbonylatively cyclized to (Z)-alkylidenefuranones in good yields under carbon monoxide pressure in DMF in the presence of a catalytic amount of a palladium catalyst along with Et3N.

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Acknowledgments

This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (2010-0007563).

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Authors and Affiliations

  1. Department of Applied Chemistry, Kyungpook National University, Daegu, 702-701, South Korea

    Chan Sik Cho & Hyo Bo Kim

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  1. Chan Sik Cho
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  2. Hyo Bo Kim
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Correspondence to Chan Sik Cho.

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Cho, C.S., Kim, H.B. Palladium-Catalyzed Carbonylative Cyclization of β-Bromo-α,β-Unsaturated Ketones Leading to Alkylidenefuranones. Catal Lett 140, 116–120 (2010). https://doi.org/10.1007/s10562-010-0457-2

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  • DOI: https://doi.org/10.1007/s10562-010-0457-2

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