Skip to main content
SpringerLink
Log in

Selective Oxidation of Glucose Over Carbon-supported Pd and Pt Catalysts

  • 2010 SSAT Plenary Presentation
  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Selective oxidation of glucose into gluconic acid by molecular oxygen over carbon-supported Pt and Pd catalysts was studied. Under examination were kinetic regularities of the process in respect of the electronic state of the noble metal surface, dispersion of the active component particles as well as substrate:Pt(Pd) ratio. Catalytic activity of the Pt/C catalysts being normalized to the dispersion of the platinum particles appeared independent of the particles mean diameter in the 1–5 nm range. A negative particle size effect for the Pd/C catalysts, caused by feasibility of oxidation of the surface of noble metal particles with the size less than 3 nm, was observed. Pt/C catalysts exhibited lower specific activity and provided poor selectivity of the glucose oxidation in comparison with Pd/C. Deactivation of Pd/C catalysts arising from the formation of surface Pd(II) oxides was retarded when the reaction was carried out under an oxygen-diffusion control.

Graphical Abstract

Selective oxidation of glucose to gluconic acid over carbon supported palladium and platinum catalysts proceeds with the selectivity up to 97 and 77%, respectively. Catalytic activity of the carbon-supported Pt nanoparticles with diameters ranging from 1 to 5 nm towards the selective oxidation of glucose is directly proportional to platinum surface area. Finely dispersed Pd/C catalysts (〈d Pd〉 =3 nm) are prone to deactivation due to oxidation of their surface, while larger metal particles (〈d Pd〉 =6 nm) are more tolerant and stable. The activity of Pd nanoparticles can be maintained when the process is controlled by diffusion of oxygen towards the active component of the catalyst.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Lichtenthaler FW (2002) Accounts Chem Res 35:728

    Article  CAS  Google Scholar 

  2. Green JW (1957) In: Pigman W (ed) The carbohydrates. Academic Press, New York, p 336

    Google Scholar 

  3. Isbell HS, Frush HL (1931) US Natl Bur Stand J Res 6:1145

    CAS  Google Scholar 

  4. Heyns K, Paulsen H (1957) Angew Chem 69:600

    Article  CAS  Google Scholar 

  5. Valetsky PM, Sulman MG, Bronstein LM, Sulman EM, Sidorov AI, Matveeva VG (2009) Nanotech Russia 4:647

    Article  Google Scholar 

  6. Mallat T, Baiker A (1994) Catal Today 19:247

    Article  CAS  Google Scholar 

  7. Pina CD, Falletta E, Prati L, Rossi M (2008) Chem Soc Rev 37:2077

    Article  Google Scholar 

  8. Pyrjaev PA, Moroz BL, Zjuzin DA, Nartova AV, Bukhtiyarov VI (2010) Kinet Catal (in press)

  9. Besson M, Gallezot P (2000) Catal Today 57:127

    Article  CAS  Google Scholar 

  10. Abbadi A, van Bekkum H (1995) J Mol Catal Chem 97:111

    Article  CAS  Google Scholar 

  11. Besson M, Lahmer F, Gallezot P, Fuertes P, Fleche G (1995) J Catal 152:116

    Article  CAS  Google Scholar 

  12. Dirkx JMH, van der Baan HS (1981) J Catal 67:1

    Article  CAS  Google Scholar 

  13. Kiyoura T, Kimura T, Sugiura T (1976) Japan Kokai 76:52,121; 85:160,467r

  14. Nakayama M, Kimura A, Eguchi H, Matsui T (1982) Eur Pat Appl EP 48:974; 97:39, 31 le

  15. Comotti M, Pina CD, Rossi M (2006) J Mol Catal Chem 251:89

    Article  CAS  Google Scholar 

  16. Dirkx JMH, van der Baan HS (1981) J Catal 67:14

    Article  CAS  Google Scholar 

  17. Yermakov YI, Surovikin VF, Plaksin GV, Semikolenov VA, Likholobov VA, Chuvilin AL, Bogdanov SV (1987) React Kinet Catal Lett 33:435

    Article  CAS  Google Scholar 

  18. Kholodovich AN, Simonov PA, Kvon RI, Bukhtiyarov AV, Zaikovskii VI, Chesalov YuA, Romanenko AV (2008) Kinet Catal 49:886

    Article  CAS  Google Scholar 

  19. Simakova OA, Simonov PA, Romanenko AV, Simakova IL (2008) React Kinet Catal Lett 95:3

    Article  CAS  Google Scholar 

  20. Semikolenov VA, Lavrenko SP, Zaikovskii VI (1993) React Kinet Catal Lett 51:507

    Article  CAS  Google Scholar 

  21. Sarcany J, Gonzalez RD (1982) J Catal 76:75

    Article  Google Scholar 

  22. Anderson JR (1975) Structure of metallic catalysts. Academic Press, London

    Google Scholar 

  23. Moulder JF, Stickle WF, Sobol PE, Bomben KD (1992) Handbook of X-ray photoelectron spectroscopy. Perkin-Elmer, Eden Prairie

    Google Scholar 

  24. Bastl Z, Přibyl O, Mikušík P (1984) Czechoslovak J Phys 34:981

    Article  Google Scholar 

  25. Mason MG (1983) Phys Rev B 27:748

    Article  CAS  Google Scholar 

  26. Angyal A (2001) In: Stutz AF (ed) Glycoscience: epimerization, isomerization and rearrangement reactions of carbohydrates. Springer-Verlag, Berlin, p 43

  27. Essis Yei LH, Beden B, Lamy C (1988) J Electroanal Chem 246:349

    Article  Google Scholar 

  28. Mehltretter CL, Rist CE, Alexander BH (1949) US Patent 2.472.168

  29. Lide (ed) (2003–2004) Handbook of chemistry and physics, 84th edn. CRC Press, Boca Raton

    Google Scholar 

  30. Gallezot P (1997) Catal Today 37:405

    Article  CAS  Google Scholar 

  31. Khan MIA, Mirva Y, Morcita S, Okada J (1981) Chem Pharm Bull 29:1795

    Google Scholar 

  32. Besson M, Fleche G, Fuertes P, Gallezot P, Lahmer F (1996) Recueil des Travaux Chimiques des Pays-Bas 115:217

    Article  CAS  Google Scholar 

  33. Van Dam HE, Kieboom APG, van Bekkum H (1987) Appl Catal 33:361

    Article  Google Scholar 

  34. Van Dam HE, Duijverman P, Kieboom APG, van Bekkum H (1987) Appl Catal 33:373

    Article  Google Scholar 

Download references

Acknowledgments

The authors are grateful to Dr. V. I. Zaikovskii for TEM characterization of catalysts, Dr. R. I. Kvon and A. V. Bukhtiyarov for XPS studies. The financial support of RFBR (Grant No. 08-03-00823), the Federal Special Programm “Scientific and Educational Cadres of Innovative Russia” via contracts NN 02.740.11.0265 and 02.740.11.5178 is gratefully acknowledged.

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis SB RAS, Akad. Lavrentiev Prosp., 5, Novosibirsk, 630090, Russia

    Irina V. Delidovich, Oxana P. Taran, Lyudmila G. Matvienko, Alexander N. Simonov, Irina L. Simakova, Alesya N. Bobrovskaya & Valentin N. Parmon

  2. Novosibirsk State University, Pirogova St., 2, Novosibirsk, 630090, Russia

    Oxana P. Taran, Lyudmila G. Matvienko, Alexander N. Simonov & Valentin N. Parmon

Authors
  1. Irina V. Delidovich
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Oxana P. Taran
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Lyudmila G. Matvienko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Alexander N. Simonov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Irina L. Simakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Alesya N. Bobrovskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Valentin N. Parmon
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Irina V. Delidovich.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Delidovich, I.V., Taran, O.P., Matvienko, L.G. et al. Selective Oxidation of Glucose Over Carbon-supported Pd and Pt Catalysts. Catal Lett 140, 14–21 (2010). https://doi.org/10.1007/s10562-010-0430-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-010-0430-0

Keywords

Search

Navigation