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Mesostructured or Alumina-mesostructured Silica SBA-16 as Potential Support for NOx Reduction and Ethanol Oxidation

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Abstract

The synthesis of some mesostructured silica or aluminosilica SBA-16 and Al-SBA-16 with 3D cubic structure is reported in this paper. The structural and porosity properties of these materials were studied by XRD, N2 sorption and TEM imaging; the Al insertion was determined by 27Al-MAS-NMR and acidic properties were characterized by pyridine adsorption followed by FT-IR spectroscopy. These solids were tested in the selective catalytic reduction of NOx by ethanol in the presence of O2. Compared to hexagonal mesoporous silica or aluminosilica (SBA-15 and Al-SBA-15), SBA-16 type materials (SBA-16 and Al-SBA-16) could be used as potential catalyst for the oxidation reaction and the SBA-16 solid has higher catalytic properties for the reduction of NOx to N2 at high temperature.

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Acknowledgment

The authors thank M. Charles Corredor from Grove School of Engineering- City College of New York.

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Authors and Affiliations

  1. Faculté des sciences II, Laboratoire de Chimie Physique des Matériaux (LCPM), Université Libanaise, Campus Fanar, BP 90656, Jdeideh, Lebanon

    Maya Boutros

  2. UPMC Univ Paris 06, CNRSFRE 3230, Laboratoire de Réactivité de Surface, Case 178, 4, Place Jussieu, 75252, Paris Cedex 05, France

    Thomas Onfroy

  3. Laboratoire Réactivité de Surface, UMR CNRS 7197, Université Pierre et Marie Curie, UPMC Paris 6, Université Pierre et Marie Curie, Case178, 4 Place Jussieu, 75252, Paris 05, France

    Patrick Da Costa

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  1. Maya Boutros
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  2. Thomas Onfroy
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  3. Patrick Da Costa
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Correspondence to Patrick Da Costa.

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Boutros, M., Onfroy, T. & Da Costa, P. Mesostructured or Alumina-mesostructured Silica SBA-16 as Potential Support for NOx Reduction and Ethanol Oxidation. Catal Lett 139, 50–55 (2010). https://doi.org/10.1007/s10562-010-0391-3

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  • DOI: https://doi.org/10.1007/s10562-010-0391-3

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