Skip to main content
SpringerLink
Log in

Nature, Environment and Quantification of Titanium Species in TiSiBEA Zeolites Investigated by XRD, NMR, DR UV–Vis and XPS

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Ti x SiBEA zeolites (x = 1.5, 3.2 and 5.8 Ti wt%) are prepared by a two-step postsynthesis method involving (1) dealumination of TEABEA zeolite by nitric acid leading to nests of SiO–H groups in vacant T-atom sites and (2) incorporation of Ti into SiBEA zeolite by reacting TiCl4 vapor with those silanol groups. The incorporation of Ti into the SiBEA framework is evidenced by XRD, 29Si MAS NMR, 1H–29Si CP MAS NMR and 1H MAS NMR. DR UV–vis and XPS investigations show that, for low Ti content, mainly framework tetrahedral Ti(IV) ions are present in Ti x SiBEA zeolites. On the basis of XPS data, the quantification of framework tetrahedral Ti(IV) and framework and/or extra-framework octahedral Ti(IV) ions is followed as a function of Ti content.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Reddy JS, Sayari A (1995) J Chem Soc Chem Commun 23

  2. Thangaraj A, Sivasanker S, Ratnasamy P (1991) J Catal 131:394

    Article  CAS  Google Scholar 

  3. Kraushaar B, van Hooff JHC (1988) Catal Lett 1:81

    Article  CAS  Google Scholar 

  4. Dzwigaj S, Peltre MJ, Massiani P, Davidson A, Che M, Sen T, Sivasanker S (1998) J Chem Soc Chem Commun 87

  5. Dzwigaj S, Matsuoka M, Franck R, Anpo M, Che M (1998) J Phys Chem B 102:6309

    Article  CAS  Google Scholar 

  6. Dzwigaj S, Che M (2006) J Phys Chem B 110:12490

    Article  CAS  Google Scholar 

  7. Janas J, Machej T, Gurgul J, Socha RP, Che M, Dzwigaj S (2007) Appl Catal B 75:239

    Article  CAS  Google Scholar 

  8. Dzwigaj S, Janas J, Machej T, Che M (2007) Catal Today 119:133

    Article  CAS  Google Scholar 

  9. Dzwigaj S, Stievano L, Wagner FE, Che M (2007) J Phys Chem Solids 68:1885

    Article  CAS  Google Scholar 

  10. Dzwigaj S, Janas J, Mizera J, Gurgul J, Socha RP, Che M (2008) Catal Lett 126:36

    Article  CAS  Google Scholar 

  11. Nogier JP, Millot Y, Man PP, Shishido T, Che M, Dzwigaj S (2009) J Phys Chem C

  12. Chiker F, Nogier JP, Launay F, Bonardet JL (2004) Appl Catal A 259:153

    Article  CAS  Google Scholar 

  13. Bourgeat-Lami E, Fajula F, Anglerat D, des Courières T (1993) Microporous Mater 1:237

    Article  Google Scholar 

  14. Dzwigaj S, Matsuoka M, Anpo M, Che M (2000) J Phys Chem B 104:6012

    Article  CAS  Google Scholar 

  15. Blasco T, Camblor MA, Corma A, Esteve P, Guil JM, Martinez A, Pedrigon-Melon JA, Valencia S (1998) J Phys Chem B 102:75

    Article  CAS  Google Scholar 

  16. Fyfe CA, Strobl H, Kokotailo GT, Pasztor CT, Barlow GE, Bradley S (1988) Zeolites 8:132

    Article  CAS  Google Scholar 

  17. Pazé C, Zecchina A, Spera S, Cosma A, Merlo E, Spano G, Girotti G (1999) Phys Chem Chem Phys 1:2627

    Article  Google Scholar 

  18. Beck LW, Haw JF (1995) J Phys Chem 99:1076

    Article  CAS  Google Scholar 

  19. Beck LW, White JL, Haw JF (1994) J Am Chem Soc 116:9657

    Article  CAS  Google Scholar 

  20. Woolery GI, Alemany LB, Dessau RM, Chester AW (1986) Zeolites 6:14

    Article  CAS  Google Scholar 

  21. Zecchina A, Bordiga S, Spoto G, Marchese L, Petrini G, Leofanti G, Padovan M (1992) J Phys Chem 96:4991

    Article  CAS  Google Scholar 

  22. Maciel GE, Ellis PD (1994) In: Bell AT, Pines A (eds) NMR Techniques in Catalysis. Dekker, New York, p 231

  23. Klein S, Weckhuysen BM, Martens JA, Majer WF, Jacobs PA (1996) J Catal 163:489

    Article  CAS  Google Scholar 

  24. Klass J, Schultz-Ekloff G, Jaeger NI (1997) J Phys Chem B 101:1305

    Article  Google Scholar 

  25. Marchese L, Maschmeyer T, Gianotti E, Coluccia S, Thomas JM (1997) J Phys Chem B 101:8836

    Article  CAS  Google Scholar 

  26. Carati A, Flego C, Massana EP, Millini R, Carluccio L, Parker WO Jr, Bellussi G (1999) Microporous Mesoporous Mater 30:137

    Article  CAS  Google Scholar 

  27. Lin K, Pescarmona PP, Vandepitte H, Liang D, Van Tendeloo G, Jacobs PA (2008) J Catal 254:64

    Article  CAS  Google Scholar 

  28. Geobaldo F, Bordiga S, Zecchina A, Giamello E, Leofanti G, Petrini G (1992) Catal Lett 16:109

    Article  CAS  Google Scholar 

  29. Fejes P, Nagy JB, Halasz J, Oszko A (1998) Appl Catal A 175:89

    Article  CAS  Google Scholar 

Download references

Acknowledgment

S. Dzwigaj gratefully acknowledges the CNRS (France) for financing his research position.

Author information

Authors and Affiliations

  1. Laboratoire des Systèmes Interfaciaux à l’Echelle Nanométrique, UPMC University of Paris 6, UMR 7142, 4 Place Jussieu, 75252, Paris Cedex 05, France

    Jean-Philippe Nogier, Yannick Millot & Pascal P. Man

  2. Laboratoire des Systèmes Interfaciaux à l’Echelle Nanométrique, CNRS, UMR 7142, 4 Place Jussieu, 75252, Paris Cedex 05, France

    Jean-Philippe Nogier, Yannick Millot & Pascal P. Man

  3. Laboratoire de Réactivité de Surface, UPMC University of Paris 6, UMR 7197, 4 Place Jussieu, 75252, Paris Cedex 05, France

    Christophe Méthivier, Michel Che & Stanislaw Dzwigaj

  4. Laboratoire de Réactivité de Surface, CNRS, UMR 7197, 4 Place Jussieu, 75252, Paris Cedex 05, France

    Christophe Méthivier, Michel Che & Stanislaw Dzwigaj

  5. Institut Universitaire de France, Paris, France

    Michel Che

Authors
  1. Jean-Philippe Nogier
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yannick Millot
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Pascal P. Man
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Christophe Méthivier
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Michel Che
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Stanislaw Dzwigaj
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Stanislaw Dzwigaj.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nogier, JP., Millot, Y., Man, P.P. et al. Nature, Environment and Quantification of Titanium Species in TiSiBEA Zeolites Investigated by XRD, NMR, DR UV–Vis and XPS. Catal Lett 130, 588–592 (2009). https://doi.org/10.1007/s10562-009-9960-8

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-009-9960-8

Keywords

Search

Navigation