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Direct Synthesis of Hydrogen Peroxide from Hydrogen and Oxygen Over Palladium Catalysts Supported on SO3H-Functionalized SiO2 and TiO2

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Abstract

Palladium catalysts supported on SO3H-functionalized SiO2 and TiO2 (denoted as Pd/SO3H-SiO2 and Pd/SO3H-TiO2) were applied to the direct synthesis of hydrogen peroxide from hydrogen and oxygen. For comparison, palladium catalysts supported on bare SiO2 and TiO2 (denoted as Pd/SiO2 and Pd/TiO2) were also employed to the direct synthesis of hydrogen peroxide from hydrogen and oxygen. Selectivity and yield for hydrogen peroxide over Pd/SO3H-SiO2 and Pd/SO3H-TiO2 catalysts were higher than those over Pd/SiO2 and Pd/TiO2 catalysts. SO3H-functionalized SiO2 and TiO2 supports efficiently served as an alternate acid source in the direct synthesis of hydrogen peroxide from hydrogen and oxygen.

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Acknowledgments

The authors wish to acknowledge supports from Ministry of Knowledge Economy and SK Energy Corporation.

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Authors and Affiliations

  1. School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Shinlim-dong, Kwanak-ku, Seoul, 151-744, South Korea

    Sunyoung Park, Ji Chul Jung, Jeong Gil Seo & In Kyu Song

  2. SK Energy Corporation, Yuseong-ku, Daejeon, 305-712, South Korea

    Tae Jin Kim, Young-Min Chung & Seung-Hoon Oh

Authors
  1. Sunyoung Park
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  2. Ji Chul Jung
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  3. Jeong Gil Seo
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  4. Tae Jin Kim
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  5. Young-Min Chung
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  6. Seung-Hoon Oh
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  7. In Kyu Song
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Correspondence to In Kyu Song.

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Park, S., Jung, J.C., Seo, J.G. et al. Direct Synthesis of Hydrogen Peroxide from Hydrogen and Oxygen Over Palladium Catalysts Supported on SO3H-Functionalized SiO2 and TiO2 . Catal Lett 130, 604–607 (2009). https://doi.org/10.1007/s10562-009-9946-6

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  • DOI: https://doi.org/10.1007/s10562-009-9946-6

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