Abstract
The deoxygenation experiments of different reactants, i.e., pure palmitic acid, stearic acid, and a technical grade stearic acid containing a mixture of 59% of palmitic and 40% of stearic acid were successfully performed over 4 wt% Pd/C mesoporous catalyst at 300 °C under 17 bar of 5% H2 in argon. The main product in catalytic deoxygenation of saturated fatty acids, C16 and C18, were aliphatic chain length hydrocarbons containing one less carbon than the corresponding acid. Additionally it was found that the deoxygenation rates of different reactant were independent on carbon chain length of its fatty acids.
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References
Ramadhas AS, Jayaraj S, Muraleedharan C (2004) Renew Energy 29:727
Gerpen JV (2005) Fuel Process Technol 86:1097
Addison K (2008) Oil yields and characteristic. Journey to forever http://journeytoforever.org/biodiesel_yield.html accessed 9 Jan 2009
Ma F, Hanna MA (1999) Bioresource Technol 70:1
Xie W, Peng H, Chen L (2006) App Catal A: Gen 300:67
Ghadge SV, Raheman H (2005) Biomass and Bioenergy 28:601
Kubickova I, Snåre M, Eränen K, Mäki-Arvela P, Murzin DYu (2005) Catal Today 106:197
Lestari S, Simakova I, Tokarev A, Mäki-Arvela P, Eränen K, Murzin DYu (2008) Catal Lett 122:247
Snåre M, Murzin DYu (2006) Ind Eng Chem Res 45:6875
Mäki-Arvela P, Kubickova I, Eränen K, Snåre M, Murzin DYu (2007) Energy Fuels 21:30
Snåre M, Kubickova I, Mäki-Arvela P, Eränen K, Wärnå J, Murzin DYu (2007) Chem Eng J 134:29
Snåre M, Kubickova I, Mäki-Arvela P, Chichova D, Eränen K, Murzin DYu (2008) Fuel 87:933
Murzin DYu, Kubickova I, Snåre M, Mäki-Arvela P, Myllyoja J (2006) PCT International application WO2006-FI50031 20060116, p 21
Snåre M, Kubickova I, Mäki-Arvela P, Eränen K, Murzin DYu (2006) Ind Eng Chem Res 45:5708
Simakova I, Simakova O, Mäki-Arvela P, Simakov A, Estrada M, Murzin DYu (2009) Appl Catal A: Gen (accepted)
Simonov P, Troitskii S, Likholobov V (2000) Kinet Catal 41:255
Simakova I, Simakova O, Mäki-Arvela P, Murzin DYu (2008) Proceedings of the 3rd International symposium on carbon for catalysis, CarboCat III, Berlin, p 105
Acknowledgments
This work is part of the activities at the Åbo Akademi University Process Chemistry Centre within the Finnish Centre of Excellence Program (2000–2011) appointed by the Academy of Finland. S. L. would like to acknowledge also the travel grant support by ARC Centre of Excellence for Functional Nanomaterials, University of Queensland, Australia and Johan Gadolin Scholarship Process Chemistry Centre Åbo Akademi University. The authors are grateful to Mr. S. Lindholm from Process Chemistry Centre, Åbo Akademi for performing ICP-OES measurements.
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Lestari, S., Mäki-Arvela, P., Simakova, I. et al. Catalytic Deoxygenation of Stearic Acid and Palmitic Acid in Semibatch Mode. Catal Lett 130, 48–51 (2009). https://doi.org/10.1007/s10562-009-9889-y
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DOI: https://doi.org/10.1007/s10562-009-9889-y