Skip to main content
SpringerLink
Log in

Catalytic Behaviors of Amorphous Co-B Catalysts in Hydroformylation of 1-Octene

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

An amorphous Co-B catalyst was prepared by chemical reduction method and characterized by isothermal N2 adsorption/desorption, XRD, ICP-AES and HR-TEM. The catalytic activity of the Co-B catalyst in the hydroformylation of 1-octene was evaluated in a 100 mL stainless autoclave. Fresh amorphous Co-B catalyst showed a relatively high activity in the hydroformylation of 1-octene. The thermal stability of fresh Co-B catalyst was also examined. When fresh Co-B catalyst was thermally treated in N2 or H2 atmosphere at 200–500 °C for 2 h, the specific surface area and the catalytic activity of the Co-B catalyst decreased. When Co-B was supported on SiO2, the activity of the catalyst increased obviously. Compared with conventional supported Co/SiO2 catalyst, Co-B/SiO2 showed much higher activity than Co/SiO2. The influences of solvents and reaction conditions on the catalytic activity of the amorphous Co-B catalyst were also studied. The recycle test of the amorphous Co-B catalyst was done.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Ungvary F (1997) Coord Chem Rev 167:233

    CAS  Google Scholar 

  2. Fell B (1998) Tenside Surfactants Detergents 35(5):326

    CAS  Google Scholar 

  3. Paulik FE (1972) Catal Rev 6:49

    Article  CAS  Google Scholar 

  4. Beller M, Cornils B, Frohning CD, Kohlpaintner CW (1995) J Mol Catal A 104:17

    Article  CAS  Google Scholar 

  5. Dieguez M, Pamies O, Claver C (2004) Tetrahedron Asymmetr 15(14):2113

    Article  CAS  Google Scholar 

  6. Klingler RJ, Chen MJ, Rathke JW, Kramarz KW (2007) Organometallics 26(2):352

    Article  CAS  Google Scholar 

  7. Lin Q, Jiang WD, Fu HY, Chen H, Li XJ (2007) Appl Catal A 328(1):83

    Article  CAS  Google Scholar 

  8. Riisager A, Eriksen KM, Hjortkjaer J, Fehrmann R (2003) J Mol Catal A 193(1–2):259

    CAS  Google Scholar 

  9. Fu HY, Li M, Chen H, Li XJ (2006) J Mol Catal A 259(1–2):156

    CAS  Google Scholar 

  10. Fierro JLG, Merchan MD, Rojas S, Terreros P (2001) J Mol Catal A 166(2):255

    Article  CAS  Google Scholar 

  11. Kainulainen TA, Nieme MK, Krause AOI (1997) J Mol Catal A 122:39

    Article  CAS  Google Scholar 

  12. Kainulainen TA, Niemela MK, Krause AOI (1999) J Mol Catal A 140:173

    Article  CAS  Google Scholar 

  13. Li B, Li X, Asami K, Fujimoto K (2003) Energy Fuels 17:810

    Article  CAS  Google Scholar 

  14. Sordelli L, Guidotti M, Andreatta D, Vlaic G, Psaro R (2003) J Mol Catal A 204–205:509

    Google Scholar 

  15. Zhang Y, Nagasaka K, Qiu X, Tsubaki N (2004) Appl Catal A 276:103

    Article  CAS  Google Scholar 

  16. Zhang Y, Nagasaka K, Qiu X, Tsubaki N (2005) Catal Today 104:48

    Article  CAS  Google Scholar 

  17. Zhang H, Qiu J, Liang C, Li Z, Wang X, Wang Y, Feng Z, Li C (2005) Catal Lett 101:211

    Article  CAS  Google Scholar 

  18. Zhu H, Ding Y, Yan L, He D, Wang T, Chen W, Lin L (2004) Chinese J Catal 25(8):653

    CAS  Google Scholar 

  19. Chen YZ, Liaw BJ, Chiang SJ (2005) Appl Catal A 284:97

    Article  CAS  Google Scholar 

  20. Chiang SJ, Yang CH, Chen YZ, Liaw BJ (2007) Appl Catal A 326(2):180

    Article  CAS  Google Scholar 

  21. Ma Y, Li W, Zhang M, Zhou Y, Tao K (2003) Appl Catal A 243(2):215

    Article  CAS  Google Scholar 

  22. Ge S, Wu Z, Zhang M, Li W, Tao K (2006) Ind Eng Chem Res 45:2229

    Article  CAS  Google Scholar 

  23. Wu C, Wu F, Bai Y, Yi BL, Zhang HM (2005) Mater Lett 59:1748

    Article  CAS  Google Scholar 

  24. Wonterghem JV, Morup S, Koch CJW, Charles SW, Wells S (1986) Nature 322:622

    Article  CAS  Google Scholar 

  25. Zong BN (2007) Catal Surv Asia 11:87

    Article  CAS  Google Scholar 

  26. Ma ZY, Zhang LX, Chen RZ, Xing WH, Xu NP (2008) Chem Eng J 138:517

    Article  CAS  Google Scholar 

  27. Jiang Z, Yang HW, Wei Z, Xie Z, Zhong WJ, Wei SQ (2005) Appl Catal A 279:165

    Article  CAS  Google Scholar 

  28. Falbe J (1980) New synthesis with carbon monoxide. Springer, New York

    Google Scholar 

  29. He DH, Pang DC, Chen Y, Wang TE, Liu Y, Liu JY, Zhu QM (2001) J Mol Catal A 174:21

    Article  CAS  Google Scholar 

  30. Brewester EAV, Pruett RL (1977) UCC company, US Patent 4247486

  31. Reichardt C (1990) Solvents and solvent effects in organic chemistry. VCH, Weinheim

    Google Scholar 

  32. Massick SM, Bulttner T, Ford PC (2003) Inorg Chem 42(2):575

    Article  CAS  Google Scholar 

  33. Goh SK, Marynick DS (2002) Organometallics 21:2262

    Article  CAS  Google Scholar 

  34. Suvanto S, Hirva P, Pakkanen TA (2000) Surf Sci 465:277

    Article  CAS  Google Scholar 

  35. Piacenti F, Calderazzo F, Bianchi M, Rosi L, Frediani P (1997) Organometallics 16:4235

    Article  CAS  Google Scholar 

  36. Moroz BL, Moudrakovski IL, Likholobov VA (1996) J Mol Catal A 112:217

    Article  CAS  Google Scholar 

  37. Usami S, Nishimura K, Koyama T, Fukushi S (1969) Bull Chem Soc Jpn 2:2966

    Article  Google Scholar 

  38. Cornils B, Herrmann WA (1996) Applied homogeneous catalysis with organometallic compounds. VCH, Weinheim

    Book  Google Scholar 

  39. Abboud JLM, Notario R (1999) Pure Appl Chem 71:645

    Article  CAS  Google Scholar 

  40. Stark A, Ajam M, Green M, Raubenheimer HG, Ranwell A, Ondruschka B (2006) Adv Synth Catal 348:1934

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work is supported by the National Natural Science Foundation of China (20373031) and the Analytical Foundation of Tsinghua University, China.

Author information

Authors and Affiliations

  1. Innovative Catalysis Program, Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, 100084, Beijing, China

    Lan Ma, Qingrong Peng & Dehua He

  2. Institute of Chemical Defence, 102205, Beijing, China

    Lan Ma

Authors
  1. Lan Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Qingrong Peng
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Dehua He
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Dehua He.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ma, L., Peng, Q. & He, D. Catalytic Behaviors of Amorphous Co-B Catalysts in Hydroformylation of 1-Octene. Catal Lett 130, 137–146 (2009). https://doi.org/10.1007/s10562-009-9839-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-009-9839-8

Keywords

Search

Navigation