Abstract
In this paper, nitrous oxide decomposition over a series of MCO3–Co3O4 (M = Ca, Sr, Ba) catalysts having M/Co ratios of 0.1–0.4 has been studied. The various catalysts were characterized using thermal (TGA, DTA), XRD, IR and N2 sorption techniques. N2O decomposition activity was found to be dependent on the type of the alkaline earth cation, the M/Co ratio, cobalt oxide crystallites sizes, and the calcination temperature.
This is a preview of subscription content, access via your institution.









References
Winter ERS (1959) Discuss Faraday Soc 28:183
Pérez-Ramírez J (2007) Appl Catal B 70:31
Pérez-Ramírez J, Kapteijn F, Schöffel K, Moulijn JA (2003) Appl Catal B 44:117
Centi G, Perathoner S, Vazzana F, Marella M, Tomaselli M, Mantegazza M (2000) Adv Environ Res 4:325
Khalil MKK (2000) Chemosphere-Glob Chang Sci 2:233
de Correa CM, Villa AL, Zapata M (1996) Catal Lett 38:27
Du J, Kuang W, Xu H, Shen W, Zhao D (2008) Appl Catal B 84:490
Orita H, Kondoh H, Nozoye H (1998) J Catal 177:217
Abu-Zied BM (2008) Appl Catal A 334:234
Haber J, Machej T, Janas J, Nattich M (2004) Catal Today 90:15
Haber J, Nattich M, Machej T (2008) Appl Catal B 77:278
Perez-Alonso FJ, Melián-Cabrera I, López Granados M, Kapteijn F, Fierro JLG (2006) J Catal 239:340
Xue L, Zhang C, He H, Teraoka Y (2007) Catal Today 126:449
Bennici S, Gervasini A (2006) Appl Catal B 62:336
Boissel V, Tahir S, Koh CA (2006) Appl Catal B 64:234
Alini S, Basile F, Blasioli S, Rinaldi C, Vaccari A (2007) Appl Catal B 70:323
Yan L, Ren T, Wang X, Ji D, Suo J (2003) Appl Catal B 45:85
Xue L, Zhang C, He H, Teraoka Y (2007) Appl Catal B 75:167
Ohnishi C, Asano K, Iwamoto S, Chikama K, Inoue M (2007) Catal Today 120:145
Pasha N, Lingaiah N, Seshu Babu N, Siva Sankar Reddy P, Sai Prasad PS (2008) Catal Commun 10:132
Stelmachowski P, Maniak G, Kotarba A, Sojka Z (2009) Catal Commun 10:1062
Asano K, Ohnishi C, Iwamoto S, Shioya Y, Inoue M (2008) Appl Catal B 78:242
Shen Q, Li L, Li J, Tian H, Hao Z (2009) J Hazard Mater 163:1332
Sundararajan R, Srinivasan V (1996) Appl Catal A 141:45
Zasada F, Stelmachowski P, Maniak G, Paul J-F, Kotarba A, Sojka Z (2009) Catal Lett 127:126
Gunasekaran N, Rajadurai S, Carberry JJ (1995) Catal Lett 35:373
Obalová L, Fíla V (2007) Appl Catal B 70:353
Obalová L, Jirátová K, Kovanda F, Pacultová K, Lacný Z, Mikulova Z (2005) Appl Catal B 60:289
Cheng H, Huang Y, Wang A, Li L, Wang X, Zhang T (2009) Appl Catal B 89:391
Groen JC, Brückner A, Berrier E, Maldonado L, Moulijn JA, Pérez-Ramírez J (2006) J Catal 243:212
Pirngruber GD, Roy PK, Prins R (2007) J Catal 246:147
Øygarden AH, Pérez-Ramírez J (2006) Appl Catal B 65:163
Melián-Cabrera I, Espinosa S, Groen JC, v/d Linden B, Kapteijn F, Moulijn JA (2006) J Catal 238:250
Abu-Zied BM, Schwieger W, Unger A (2008) Appl Catal B 84:277
Park J-H, Choung J-H, Nam I-S, Ham S-W (2008) Appl Catal B 78:342
Smeets PJ, Meng Q, Corthals S, Leeman H, Schoonheydt RA (2008) Appl Catal B 84:505
Roy PK, Prins RP, Pringruber GD (2008) Appl Catal B 80:226
Pasha N, Lingaiah N, Siva Sankar Reddy P, Sai Prasad PS (2009) Catal Lett 127:101
Pasha N, Lingaiah N, Siva Sankar Reddy P, Sai Prasad PS (2007) Catal Lett 118:64
Leofanti G, Padovan M, Tozzola G, Venturelli B (1998) Catal Today 41:207
Mohamed MA, Halawy SA, Ebrahim MM (1994) J Thermal Anal 41:387
Wanjun T, Donghua C (2007) Chem Pap 61:329
Arvanitidis I, Sichen D, Sohn HY, Seetharaman S (1997) Metall Mater Trans B 28:1063
Omran ZA, Mousa MA, Abdel Fattah AA, Diefallah E-HM (1989) Thermochim Acta 145:271
Samtani M, Dollimore D, Alexander KS (2002) Thermochim Acta 392–393:135
Al-Hajji LA, Hassan MA, Zaki MI (2009) Thermochim Acta 483:8
Shaheen WM, Selim MM (2001) Inter J Inorg Mater 3:417
Milt VG, Ulla MA, Miró EE (2005) Appl Catal B 57:13
Kustova GN, Burgina EB, Volkova GG, Yurieva TM, Plyasova LM (2000) J Mol Catal A 158:293
Wang Y-Z, Zhao Y-X, Gao C-G, Liu D-S (2007) Catal Lett 116:136
Gadsden JA (1975) Infrared spectra of minerals and related inorganic compounds. Butterworths, London, p 62
Ismail HM (1996) Colloids Surf A 1l0:159
Fouad NE, Knözinger H, Ismail HM, Zaki MI (1991) Z Phys Chem 173:201
Yamashita T, Vannice A (1996) J Catal 161:254
Drago RS, Jurczyk K, Kob N (1997) Appl Catal B 13:69
Abu-Zied BM, Schwieger W (2009) Appl Catal B 85:120
Xiao Q, Zhang J, Xiao C, Tan X (2008) Catal Commun 9:1247
Tschumper GS, Schaefer HF (1997) J Chem Phys 107:2529
Zecchina A, Cerruti L, Borello E (1972) J Catal 25:55
Indovina V, CordischiI D, Occhiuzzi M, Rieti A (1979) J Chem Soc Faraday Trans 1 75:2177
Chang Y-F, McCarty JG, Wachsman ED (1995) Appl Catal B 6:21
Chao CC, Lunsford JH (1971) J Amer Chem Soc 93:71
de Lara EC, Vincent-Geisse JV (1972) J Phys Chem 76:945
Angelidis TN, Tzitzios V (2003) Appl Catal B 41:357
Krishna K, Makkee M (2006) Catal Lett 106:183
Hensen EJM, Zhu Q, Hendrix MMRM, Overweg AR, Kooyman PJ, Sychev MV, van Santen RA (2004) J Catal 221:560
Acknowledgments
The authors would like to gratefully acknowledge the Deutscher Akademischer Austausch Dienst (DAAD) for the granting of the gas analyzers used in the measurements. In addition, Assiut University is gratefully acknowledged for the support of the mass follow controllers used in this investigation.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Abu-Zied, B.M., Soliman, S.A. Nitrous Oxide Decomposition Over MCO3–Co3O4 (M = Ca, Sr, Ba) Catalysts. Catal Lett 132, 299–310 (2009). https://doi.org/10.1007/s10562-009-0158-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-009-0158-x