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Ru Nanoparticles Entrapped in Mesopolymers for Efficient Liquid-phase Hydrogenation of Unsaturated Compounds

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Abstract

Ruthenium nanoparticles entrapped in periodic mesopolymers, Ru/FDU-15-H2, were proved to be an effective and reusable catalyst for the liquid-phase hydrogenation of benzaldehydes, affording a constant activity after the 6th cycle in water. Besides the hydrogenation of benzaldehydes, Ru/FDU-15-H2 catalyst can also catalyze the liquid-phase hydrogenation of arenes, olefins and other carbonyl compounds under mild conditions.

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Acknowledgments

This work was supported by the NSFC (20703018), Shanghai Rising-star Project (08QA1402700), 973 Program (2006CB202508) and Shanghai Leading Academic Discipline Project (B409). We also want to thank Dr. Difei Han at Dalian Institute of Chemical Physics, CAS for his help in taking TEM images.

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Authors and Affiliations

  1. Department of Chemistry, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 3663 North Zhongshan Rd., 200062, Shanghai, China

    Liying Song, Xiaohong Li, Hongna Wang, Haihong Wu & Peng Wu

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  1. Liying Song
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  2. Xiaohong Li
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  3. Hongna Wang
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  4. Haihong Wu
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  5. Peng Wu
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Correspondence to Xiaohong Li.

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Song, L., Li, X., Wang, H. et al. Ru Nanoparticles Entrapped in Mesopolymers for Efficient Liquid-phase Hydrogenation of Unsaturated Compounds. Catal Lett 133, 63–69 (2009). https://doi.org/10.1007/s10562-009-0130-9

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  • DOI: https://doi.org/10.1007/s10562-009-0130-9

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